STERIC AND ELECTRONIC SUBSTITUENT EFFECTS IN TERTIARY ALKYL PEROXIDE DECOMPOSITIONS

Hendrickson WH.; Nguyen JT.; Simons KT.; Nguyen CC.

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STERIC AND ELECTRONIC SUBSTITUENT EFFECTS IN TERTIARY ALKYL PEROXIDE DECOMPOSITIONS

机译：叔烷基过氧化物分解中的空间和电子取代基效应

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Rate constants for the homolysis of aryl-substituted alpha-cumyl tert-butyl peroxides (X-PhCMe(2)OOCMe(3)) produce a Hammett plot with a rho value of -0.22+/-.04. Both steric and electronic parameters influence the decomposition rate constants of tertiary alkyl peroxides with bulky substituents: log k(rel) = (-0.40+/-08)Sigma sigma* -(0.43+/-.02)Sigma(s)(c). [References: 20]

机译：均化芳基取代的α-枯基叔丁基过氧化物（X-PhCMe（2）OOCMe（3））的速率常数产生Hammett图，rho值为-0.22 +/-。04。空间参数和电子参数均会影响具有大取代基的叔烷基过氧化物的分解速率常数：log k（rel）=（-0.40 +/- 08）Sigma sigma *-（0.43 +/-。02）Sigma（s）（c ）。 [参考：20]

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《Tetrahedron letters: The International Journal for the Rapid Publication of Preliminary Communications in Organic Chemistry》 |1995年第40期|共4页
作者
Hendrickson WH.; Nguyen JT.; Simons KT.; Nguyen CC.;
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正文语种 eng
中图分类有机化学;
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Butyl;

机译：丁基胶;

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1. STERIC AND ELECTRONIC SUBSTITUENT EFFECTS IN TERTIARY ALKYL PEROXIDE DECOMPOSITIONS [J] . Hendrickson WH., Nguyen JT., Simons KT., Tetrahedron letters: The International Journal for the Rapid Publication of Preliminary Communications in Organic Chemistry . 1995,第40期

机译：叔烷基过氧化物分解中的空间和电子取代基效应
2. Synthesis and pharmacology of 1-alkyl-3-(1-naphthoyl)indoles: Steric and electronic effects of 4- and 8-halogenated naphthoyl substituents [J] . WileyJ.L., SmithV.J., ChenJ., Bioorganic and medicinal chemistry . 2012,第6期

机译：1-烷基-3-（1-萘甲酰基）吲哚的合成与药理作用：4-和8-卤代萘甲酰基取代基的立体效应和电子效应
3. Iron complexes for the catalytic transfer hydrogenation of acetophenone: Steric and electronic effects imposed by alkyl substituents at phosphorus [J] . Lagaditis P.O., Lough A.J., Morris R.H. Inorganic Chemistry: A Research Journal that Includes Bioinorganic, Catalytic, Organometallic, Solid-State, and Synthetic Chemistry and Reaction Dynamics . 2010,第21期

机译：用于苯乙酮催化转移加氢的铁配合物：磷上烷基取代基施加的立体和电子效应
4. Steric effects in the chemiluminescent reactions of metastable Ca~*(~3P) atoms with isomeric alkyl halides [C] . B. Pranszke Workshop on Atomic and Molecular Physics . 2003

机译：用异常烷基卤化物的亚稳态Ca〜*（〜3P）原子的化学发光反应的空间效应
5. THE REACTIONS OF PHENYL AND ALKYL RADICALS WITH CARBON-MONOXIDE; OBSERVATIONS ON THE INDUCED DECOMPOSITION OF BENZOYL PEROXIDE. [D] . SAVAS, EMANUEL S. -1

机译：苯和烷基自由基与一氧化碳的反应关于引起的过氧化苯甲酰分解的观察。
6. Synthesis and Pharmacology of 1-Alkyl-3-(1-naphthoyl)indoles: Steric and Electronic Effects of 4- and 8-Halogenated Naphthoyl Substituents. [O] . Jenny L. Wiley, Valerie J. Smith, Jianhong Chen, -1

机译：1-烷基-3-（1-萘酰基）吲哚的合成和药理学：4-和8-卤化萘甲酰基取代基的空间和电子效应。
7. Synthesis and pharmacology of 1-alkyl-3-(1-naphthoyl)indoles: Steric and electronic effects of 4- and 8-halogenated naphthoyl substituents [O] . Jenny L. Wiley, Valerie J. Smith, Jianhong Chen, 2012

机译：1-烷基-3-（1-萘酰基）吲哚的合成和药理学：4-和8-卤代萘酰烯基取代基的空间和电子效应
8. Chiral Synthesis via Organoboranes. 22. Selective Reductions. 44. The Effect of the Steric Requirements of the Alkyl Substituent in Isopinocampheylalkylchloroboranes for the Asymmetric Reduction of Representative Ketones [R] . Brown, H. C., Srebnik, M., Ramachandran, P. V. 1989

机译：有机硼烷的手性合成。 22.选择性削减。 44.异丙基氨基烷基氯硼烷中烷基取代基的空间要求对代表性酮的不对称还原的影响

STERIC AND ELECTRONIC SUBSTITUENT EFFECTS IN TERTIARY ALKYL PEROXIDE DECOMPOSITIONS

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