Chemical examination of the seeds of the Chinese yew, Taxus yunnanensis Cheng et L. K. Fu and japanese yew, T. cuspidata Sieb et Zucc resulted in the isolation of three new and rare rearranged abeotaxane type of diterpenoids in addition to several known compounds. The structures of the new taxoids have been established as 9#alpha#, 13#alpha#-diacetoxy-11(15 -> 1)abeotaxa-4(20), 11-diene-5#alpha#, 10#beta#, 15-triol (1), 9#alpha#, 13#alpha#-diacetoxy-10#beta#-benzoyloxy-5#alpha#-(3'-dimethylamino-3'-phenyl)-propionyloxy-11(15 -> 1)abeotaxa-4(20), 11-diene-15-ol (2), and 2#alpha#, 7#beta#, 13#alpha#-triacetoxy-10#beta#-hydroxy-5#alpha#-(3'-dimethylamino-3'-phenyl)-propionyloxy-2(3 -> 2O)-abeo-taxa-9-one (3) by a study of their spectral data.
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机译:化学检测中国红豆杉云南红豆杉Cheng et L.K. Fu和日本红豆杉T. cuspidata Sieb et Zucc的种子,除了分离出几种已知化合物外,还分离出了三种新的和罕见的重排重氮杂三恶烷类双萜。新的类紫杉醇的结构已确定为9#alpha#,13#alpha#-diacetoxy-11(15-> 1)abeotaxa-4(20),11-diene-5#alpha#,10#beta#, 15-三醇(1),9#alpha#,13#alpha#-二乙酰氧基-10#beta#-苯甲酰氧基-5#alpha#-(3'-二甲基氨基-3'-苯基)-丙酰氧基-11(15-> 1)aeotaxa-4(20),11-二烯-15-ol(2)和2#alpha#,7#beta#,13#alpha#-三乙酰氧基-10#beta#-羟基-5#alpha#-通过对它们的光谱数据的研究,(3'-二甲基氨基-3'-苯基)-丙酰氧基-2(3-> 2O)-阿拉伯-紫杉醇-9-(1)。
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