Side-chain migration reactions and ring B aromatization in labdanes: scope and limitations. Synthesis of isofregenedane type tetrahydronaphthalenic diterpenes

Marcos IS.; Basabe P.; Laderas M.; Diez D.; Jorge A.; Rodilla JM.; Moro RF.; Lithgow AM.; Barata IG.; Urones JG.

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Side-chain migration reactions and ring B aromatization in labdanes: scope and limitations. Synthesis of isofregenedane type tetrahydronaphthalenic diterpenes

机译：Labdanes中的侧链迁移反应和B环芳构化：范围和局限性。异丁烯烷型四氢萘二萜的合成

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The reaction of bicyclic diterpenes with an allylic oxygenated function or an equivalent functionality on ring B in the presence of I-2/benzene afforded a simple and rapid synthesis of tetrahydronaphthalenic diterpenes of the isofregenedane class. (C) 2003 Elsevier Science Ltd. All rights reserved. [References: 18]

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《Tetrahedron 》 |2003年第13期| 共11页
作者
Marcos IS.; Basabe P.; Laderas M.; Diez D.; Jorge A.; Rodilla JM.; Moro RF.; Lithgow AM.; Barata IG.; Urones JG.;
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正文语种 eng
中图分类有机化学 ;
关键词
Isofregenedane; Labdanes; Aromatization; Halimium-viscosum; Homochiral synthesis; Chemistry; Fregenedadiol; Verticillatum;

机译：异氟烷烷;拉丹烷;芳构化;粘稠Ha;手性合成;化学;弗雷格达纳二醇;黄萎病;

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1. Side-chain migration reactions and ring B aromatization in labdanes: scope and limitations. Synthesis of isofregenedane type tetrahydronaphthalenic diterpenes [J] . Marcos IS., Basabe P., Laderas M., Tetrahedron . 2003 ,第13期

机译：Labdanes中的侧链迁移反应和B环芳构化：范围和局限性。异丁烯烷型四氢萘二萜的合成
2. Substrate specificity of the CYC2 enzyme from Kitasatospora griseola: production of sclarene, biformene and novel bicyclic diterpenes by the enzymatic reactions of labdane-and halimane-type diterpene diphosphates [J] . Chiaki Nakano, Tsutomu Hoshino, Tsutomu Sato Tetrahedron letters: The International Journal for the Rapid Publication of Preliminary Communications in Organic Chemistry . 2010 ,第1期

机译：Kitasatospora griseola CYC2酶的底物特异性：通过拉丹烷型和哈拉曼型二萜二磷酸酯的酶促反应生产香紫苏烯，双甲醛和新型双环二萜
3. TOWARDS THE SYNTHESIS OF POLYOXYGENATED LABDANE DITERPENES - FURAN AS BUILDING BLOCK FOR THE C-RING [J] . Lange U., Blechert S., Plitzko W. Tetrahedron . 1995 ,第20期

机译：致力于合成多聚环氧乙烷的二烷-呋喃，作为C环的砌块
4. Allyl-based,C~(alpha)-methylated alpha-amino acids in the side-chain to side-chain ring-closing metathesis reaction of beta-turn/3_(10)-helical peptides [C] . Claudio Toniolo, Marco Crisma, Fernando Formaggio, the International Peptide Symposium . 2001

机译：基于烯丙基的C〜（α） - 侧链中的甲基化α-氨基酸与β转/ 3_（10） - 尿肽的侧链闭合复分解反应
5. Ring-opening-ring-closing metathesis of bicyclo[2.2.2]octenes: A novel synthesis of decalins and hydrindanes, and, Studies of the scope and source of selectivity of a chemo- and diastereoselective elimination reaction . [D] . Minger, Timothy L. 2005

机译：双环[2.2.2]辛烯的开环-开环易位：萘烷和氢化茚的新型合成方法，以及化学和非对映选择性消除反应的选择性范围和来源的研究。
6. Genus Cistus: a model for exploring labdane-type diterpenes biosynthesis and a natural source of high value products with biological aromatic and pharmacological properties [O] . Dimitra Papaefthimiou, Antigoni Papanikolaou, Vasiliki Falara, 2014

机译：Cistus属：探索拉丹烷型二萜生物合成的模型以及具有生物学芳香和药理特性的高价值产品的天然来源
7. Genus Cistus: a model for exploring labdane-type diterpenes' biosynthesis and a natural source of high value products with biological, aromatic and pharmacological properties [O] . Dimitra ePapaefthimiou, Antigoni ePapanikolaou, Vasiliki eFalara, 2014

机译：Cistus属：探索labdane型二萜的模型。生物合成和具有生物，芳香和药理特性的高价值产品的天然来源

Side-chain migration reactions and ring B aromatization in labdanes: scope and limitations. Synthesis of isofregenedane type tetrahydronaphthalenic diterpenes

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