An efficient method for aromatic Friedel-Crafts alkylation,acylation,benzoylation,and sulfonylation reactions

Ravi P.Singh; Rajesh M.Kamble; Kusum L.Chandra; P.Saravanan; Vinod K.Singh

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An efficient method for aromatic Friedel-Crafts alkylation,acylation,benzoylation,and sulfonylation reactions

机译：芳族Friedel-Crafts烷基化，酰化，苯甲酰化和磺酰化反应的有效方法

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Aromatic electrophilic substitution reactions such as alkylation,acylation,benzoylation ,and fulfonylation were studied in the presence of a catalytic amount of CU(OTf)_2 and Sn(OTf)_2.Cu(OTf)_2 was very efficient for alkylation,acylation,and benzoylation reactions.However,in case of sulfonylation reactions,Sn(OTf)_2 gave better results.

机译：在催化量的CU（OTf）_2和Sn（OTf）_2的存在下，研究了烷基化，酰化，苯甲酰化和磺酰化等芳香亲电取代反应.Cu（OTf）_2对烷基化，酰化和烷基化反应非常有效。苯甲酰化反应。但是，在进行磺酰化反应时，Sn（OTf）_2效果更好。

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《Tetrahedron》 |2001年第1期|共7页
作者
Ravi P.Singh; Rajesh M.Kamble; Kusum L.Chandra; P.Saravanan; Vinod K.Singh;
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正文语种 eng
中图分类有机化学;
关键词
aromatic riedel-crafts alkylation; acylation; benzoylation; and sulfonylation reactions; copper(II)tri-fluoromethanesulfonate; tin(II)tri-fluoromethanesulfonate;

机译：芳族蓖麻油烷基化;酰化;苯甲酰化;及磺酰化反应;三氟甲磺酸铜（II）;三氟甲磺酸锡（II）;

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1. An efficient method for aromatic Friedel-Crafts alkylation,acylation,benzoylation,and sulfonylation reactions [J] . Ravi P.Singh, Rajesh M.Kamble, Kusum L.Chandra, Tetrahedron . 2001,第1期

机译：芳族Friedel-Crafts烷基化，酰化，苯甲酰化和磺酰化反应的有效方法
2. Methanetrisulfonic Acid: A Highly Efficient Strongly Acidic Catalyst for Wagner-Meerwein Rearrangement, Friedel-Crafts Alkylation and Acylation Reactions. Examples from Vitamin E Synthesis [J] . Werner Bonrath Sustainability . 2009,第2期

机译：甲烷三磺酸：一种用于Wagner-Meerwein重排，Friedel-Crafts烷基化和酰化反应的高效强酸性催化剂。维生素E合成的例子
3. Catalytic Friedel-Crafts Acylation and Benzoylation of Aromatic Compounds Using Activated Hematite as a Novel Heterogeneous Catalyst [J] . Hashem Sharghi, Mahboubeh Jokar, Mohammad Mahdi Doroodmand Advanced synthesis & catalysis . 2010,第17期

机译：活化赤铁矿为新型非均相催化剂的芳族化合物的弗里德尔-克拉夫茨化和苯甲酰化
4. STRUCTURES AND REACTION MECHANISMS OF FRIEDEL-CRAFTS ACYLATION REACTIONS OVER ACID FAUJASITE ZEOLITE [C] . Thiltava Yutthalekha, Bundet Boekfa, Jumras Limtrakul ACS National Meeting . 2012

机译：Friedel-Crafts酰化反应对酸性沸石沸石的结构和反应机制
5. Solid acid catalysis in liquid, gas-expanded liquid and near-critical reaction media: Investigations of isobutane/butene alkylation and aromatic acylation reactions. [D] . Sarsani, VidyaSagarReddy. 2008

机译：在液体，气体膨胀的液体和近临界反应介质中的固体酸催化：异丁烷/丁烯烷基化和芳族酰化反应的研究。
6. Probing Substrate/Catalyst Effects Using QSPR Analysis on Friedel-Crafts Acylation Reactions over Hierarchical BEA Zeolites [O] . Ruben Elvas-Leitão, Filomena Martins, Leonor Borbinha, 2020

机译：使用QSPR分析对分层BEA沸石的Friedel-Crafts酰化反应的QSPR分析探测底物/催化剂效应
7. Greener Friedel-Crafts Acylation Using Microwave-Enhanced Reactivity of Bismuth Triflate in the Friedel-Crafts Benzoylation of Aromatic Compounds with Benzoic Anhydride [O] . Phuong Hoang Tran, Hai Truong Nguyen, Poul Erik Hansen, 2017

机译：Greener Friedel-Crafts酰化使用微波增强的铋的反应性，在Friedel-Crafts与苯甲酰酐的芳族化合物的苯甲酰化中的苯甲酰苯甲酸盐

An efficient method for aromatic Friedel-Crafts alkylation,acylation,benzoylation,and sulfonylation reactions

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