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OXIDATION RE-MELTING OF THE Cr13Ni CAST STEEL BY MEANS OF OXYGEN-BLOWING

机译:吹氧法对Cr13Ni铸钢的氧化重熔

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Corrosion resistant 13 percent Cr and 1 percent Ni cast steel are used to produce castings for the Kaplan, Pelton and Francis turbines. These cast steels have also a satisfactory cavitation resistance. The oxidation re-melting process, where oxygen is blown into the bath, was elaborated in order to reduce the gas content (hydrogen and nitrogen) in re-melted corrosion-resistant 13 percent Cr and 1 percent Ni steel scrap. This technology was tested on and elaborated for twenty-five melts, with special regard to oxygen-blowing conditions, mechanical properties (verified by the impact test) of the cast steel, and suppressing the formation of gas holes in the castings. Basic electric arc furnaces were used in the oxidation re-melting process of steel scrap. The measuring of bath temperature and oxygen activity in the bath, and the parallel sampling for chemical analysis of the bath were realised in the following melt periods: 1) after meltdown and heating before oxygen blowing; 2) immediately after the end of oxygen blowing; 3) at the beginning of the reduction period, after preliminary de-oxidation with Al, slag reduction and modification of chemical composition; 4) in the bath at the end of the reduction period; and 5) in the ladle, after tapping and SiCa deoxidation. Results of this measuring are given in Table 1 and the corresponding mechanical properties and impact test results for re-melted steels are in Table 2. The heat treatment of cast samples of re-melted corrosion-resistant steels was as follows: homogenisation annealing at 1150 deg C/(6-12 h - as a function of the wall thickness of castings)/(air cooling) plus hardening at 940 deg C/(4-6 h)/air cooling) and tempering at 720 deg C/(4-6 h)/(air cooling). The castings from the re-melted steel of this type were without bubbles.
机译:耐腐蚀的13%Cr和1%Ni铸钢用于生产Kaplan,Pelton和Francis涡轮机的铸件。这些铸钢还具有令人满意的抗气蚀性。精心设计了将氧气吹入熔池的氧化重熔工艺,以减少重熔的耐腐蚀的13%Cr和1%Ni钢废料中的气体含量(氢和氮)。对该技术进行了测试并针对25个熔体进行了详细说明,特别考虑了吹氧条件,铸钢的机械性能(通过冲击试验验证),并抑制了铸件中的气孔形成。基本的电弧炉用于废钢的氧化重熔过程。在以下熔解周期中,实现了熔池温度和熔池中氧活度的测量以及熔池化学分析的并行采样:1)熔解后和吹氧前加热。 2)吹氧结束后立即进行; 3)在还原期开始时,用Al进行初步脱氧,还原炉渣并改变化学成分; 4)在还原期结束时在浴中; 5)在钢包中,出钢和SiCa脱氧后。测量结果列于表1,重熔钢的相应机械性能和冲击试验结果列于表2。重熔耐腐蚀钢铸件的热处理如下:1150年均质退火摄氏度/(6-12小时-铸件壁厚的函数)/(空气冷却)加上940摄氏度/(4-6小时)/空气冷却的硬化)和720摄氏度/(4温度的回火-6小时)/(风冷)。由这种类型的重熔钢制成的铸件没有气泡。

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