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Sonochemical procedures; the main synthetic method for synthesis of coinage metal ion supramolecular polymer nano structures

机译:声化学程序;造币金属离子超分子聚合物纳米结构的主要合成方法

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摘要

During the last two decades, supramolecular polymers have received great attention and the number of their synthesized compounds is still growing. Although people have long been interested in their crystalline network form it was only until 2005 that the first examples of nano- or microscale coordination polymers particles be demonstrated. This review tries to give an overview of all nano supramolecular compounds which were reported from coinage metal ions, their attributed synthetic procedures and to investigate the relation between the dimensions of coinage metal ions (Cu, Ag and Au) coordination and supramolecular polymers with their nano-structural morphologies and dimensions. Eleven compounds (from twenty compounds) with nano-structure morphology were prepared by sonochemical process and Ag(I) coordination and supramolecular polymer nano-structures can be easily prepared by sonochemical procedures. (C) 2015 Elsevier B.V. All rights reserved.
机译:在过去的二十年中,超分子聚合物受到了极大的关注,其合成化合物的数量仍在增长。尽管人们一直对它们的晶体网络形式感兴趣,直到2005年才证明了纳米级或微米级配位聚合物颗粒的第一个实例。这篇综述试图概述造币金属离子报道的所有纳米超分子化合物及其合成方法,并探讨造币金属离子(铜,银和金)配位的尺寸与超分子聚合物与其纳米之间的关系。结构形态和尺寸。通过声化学方法制备了11种具有纳米结构形态的化合物(从20种化合物中),并且通过声化学程序可以轻松地制备Ag(I)配位和超分子聚合物纳米结构。 (C)2015 Elsevier B.V.保留所有权利。

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