ESTERIFICACAO DE ACIDOS GRAXOS UTILIZANDO ZIRCONIA SULFATADA E COMPOSITOS CARVAO ATIVADO/ZIRCONIA SULFATADA COMO CATALISADORES

摘要

In this work sulfated zirconia (SZr) and activated carbon/SZr composites produced by impregnation method with or without heating treatment step (CABC/SZr-I and CABC/SZr-I SC) and by the method of synthesis of SZr on the carbon (CABC/SZr-S) was used as catalysts in the esterification reactions of fatty acids. The SZr presented very active, conversions , higher than 90% were obtained after 2 h of reaction. The activity of the composite CABC/SZr-120%SC was up to 92%, however, this was directly related to time and temperature reactions. CABC/SZr-I and CABC/SZr-S were less active in esterification reactions, what could be attributed to its low acidity.