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Steady-State Viscoelastic Flow Simulation of Polymer Melts in a Rotational-Type Rheometer

机译:旋转流变仪中聚合物熔体的稳态粘弹性流动模拟

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摘要

Polymer samples in the jigs begins to protrude when the heat is turned up when we measure the Theological characteristics of polymer melts using rotational-type rheometers, such as parallel and cone-and-plate types. To clarify the effects of this protruding part on the obtained rheological data, we tried to evaluate the rotational-type rheometer by a non-isothermal viscoelastic flow simulation using the finite element method. The multiple mode Phan-Thien Tanner (PTT) model was employed as the constitutive equation. As a result, the shear viscosity in the steady state increases with the size of the protruding part of the polymer melt specimen at the same shear rate in case with a parallel plate and a cone-and-plate type rheomters. In contrast, the deviation of the primary normal stress difference between the estimated value from the simulation results and the data from the PTT model is almost independent of the size of the protruding part with the cone-and-plate type rheometer. In addition, the deviations of the primary normal stress difference with a parallel plate rheometer increase with the protruding part size. However, these deviations are smaller than those of shear viscosity.
机译:当我们使用旋转式流变仪(如平行平板和锥板式)测量聚合物熔体的流变特性时,当热量升高时,夹具中的聚合物样品就会开始突出。为了阐明该突出部分对获得的流变数据的影响,我们尝试通过有限元方法的非等温粘弹性流动模拟来评估旋转型流变仪。本构方程采用多模态潘·坦纳(PTT)模型。结果,在平行板和锥板式流变仪的情况下,在相同剪切速率下,稳态下的剪切粘度随着聚合物熔体样品的突出部分的尺寸而增加。相反,模拟结果的估计值与PTT模型的数据之间的主要法向应力差的偏差几乎与锥板式流变仪的突出部分的大小无关。另外,平行板流变仪的主要法向应力差的偏差随着突出部尺寸的增加而增加。但是,这些偏差小于剪切粘度。

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