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Hot-Fillable Containers Containing PET/PEN Copolymers and Blends

机译:包含PET / PEN共聚物和混合物的热灌装容器

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Bottles and containers made of PET are not suitable for hot filling since the limiting upper-use temperature of this polymer is about 85 deg C.In the present study the properties and performance of bottles made from copolymers and blends of PET containing NDC groups and manufactured by the Injection Stretch Blow Molding (ISBM) process were investigated.These compositions possess advanced properties and can be used up to 95°C.The properties of these bottles were found to depend on their composition and microstructure.The glass transition temperature,the degree of crystallinity and the induced strains that were measured by differential scanning cal-orimetry and differential mechanical thermal analysis are reported.It was concluded that NDC-containing PET based copolymers and blends could be processed by a one-stage ISBM process into containers of improved properties and hot-filling capabilities.
机译:由PET制成的瓶子和容器不适合热灌装,因为该聚合物的极限使用温度约为85摄氏度。在本研究中,由含有NDC基团的PET的共聚物和共混物制成的瓶子的性能和性能通过注射拉伸吹塑(ISBM)工艺进行了研究。这些组合物具有先进的性能,可以在高达95°C的温度下使用。发现这些瓶的性能取决于其组成和微观结构。玻璃化转变温度,程度报道了通过差示扫描量热法和差示机械热分析测量的结晶度和诱发应变。结论是,含NDC的PET基共聚物和共混物可以通过一阶段ISBM工艺加工成性能提高的容器和热灌装功能。

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