High-efficiency impact modifier prepared by coagulation emulsion polymerization through internal voiding toughening mechanism

摘要

This paper was an application of our previous study on particle coagulation mechanism (Colloid Polym Sci 291: 2385-2398, 2013), and the effect of coagulation particle of acrylic impact modifiers (ACR) on polymer blend properties was investigated. The compatibility was relevant with the properties of shell phase rather than the structure of core phase. The rubber content was found to be the main influencing factor for toughening when rubber content less than 5%. However, when it reached to 7%, the dispersion of rubber became the primary parameter to dominate the toughness. The highest impact strength of poly(vinyl chloride) (PVC) toughened by coagulation particles was 1656J/m, nearly 56 times than pure PVC, whereas only 45 times was reached when toughening by traditional ACR prepared by seeded emulsion polymerization; moreover, the brittle-ductile transition happened in advanced of 2phr at ACR content. Scanning electron microscopy results showed that the shear yielding of the matrix and rubber cavitation were the major toughening mechanisms. Furthermore, the high performance of blend responsible for coagulation particles was discussed. Copyright (c) 2014 John Wiley & Sons, Ltd.