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Polyetheretherketone Composites Reinforced With Surface Modified Mica

机译:表面改性云母增强聚醚醚酮复合材料

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Mica fillers reinforced polyetheretherketone (PEEK) composites were fabricated using compression molding technique. To improve embedding of the mica within the PEEK matrix, the mica surface was chemically modified using vinyl trimethoxysilane (VTMO), at variable concentration (0-1.5 wt%). The performance characteristics and treated mica PEEK at mica loading of 20 wt% composites were examined in terms of scanning electron microscopy, dynamic mechanical thermal analysis, and modulated differential scanning calorimetry. The tensile strength and modulus improved to the tune of 81 and 44% with treated mica-filled PEEK composites. Mechanical tests revealed improved properties of VTMO-treated mica/PEEK composites, which confirmed improved interfacial adhesion with chemical treatment. The increment of the dynamic modulus for the treated mica PEEK composites was also noticed to 82% as compared with untreated counterpart, at elevated temperatures of 250 C, indicating apparent improvement of high-temperature mechanical properties.
机译:云母填充增强聚醚醚酮(PEEK)复合材料是使用压缩成型技术制造的。为了改善云母在PEEK基质中的嵌入,使用乙烯基三甲氧基硅烷(VTMO)以可变的浓度(0-1.5%重量)对云母表面进行了化学修饰。通过扫描电子显微镜,动态机械热分析和调制差示扫描量热法检查了云母含量为20 wt%的复合材料时的性能特征和处理过的云母PEEK。经处理的云母填充的PEEK复合材料的拉伸强度和模量提高了81%和44%。力学测试表明,经VTMO处理的云母/ PEEK复合材料的性能有所改善,证实了化学处理后界面粘合性的提高。与未处理的云母PEEK复合材料相比,在250°C的高温下,处理后的云母PEEK复合材料的动态模量增量也达到了82%,这表明高温机械性能得到了明显改善。

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