SYNTHESIS AND CRYSTAL STRUCTURE OF A NOVEL OXO-BRIDGED DI-IRON(III) COMPLEX - MU-OXO[CHLOROTETRAKIS(THIAZOLE)IRON(III)] [TRICHLORO-IRON(III)]

摘要

The title compound, [ClFe(thiazole)(4)-O-FeCl3] (1) has been synthesized by the hydrolysis of anhydrous FeCl3 in an ethanol-thiazole solvent mixture. Compound 1 consists of a tetrahedrally coordinated OFeCl3 group bridged by the oxo ligand to an Fe(thiazole)(4)Cl group, wherein the thiazole groups occupy the equatorial positions in an octahedral coordination polyhedron. (C) 1997 Elsevier Science Ltd. [References: 10]