Mixed-metal coordination networks constructed from Hg(CN)2 rods and Hg?Naz (az = azide) secondary interactions: Syntheses and structures of Hg(CN)2·(N3)2· Cu(C5H5N)2 and NaHg(CN)2· (N3)2·Cu(N3)

摘要

The syntheses and crystal structures of Hg(CN)_2·(N _3)_2·Cu(C_5H_5N)_2 (1) and NaHg(CN)_2·(N_3)_2·Cu(N _3)(C_3H_(10)N_2)_2 (2) are reported. The interplay between linear Hg(CN)_2 and N3- building units by way of long Hg?N secondary interactions leads to new types of hybrid inorganic-organic networks in these phases.