Self-powered fluorescence display devices based on a fast self-charging/recharging battery (Mg/Prussian blue)

摘要

Stimuli-responsive (such as voltage and/or light) fluorescence display systems have attracted particular attention in their promising fields of application. However, there are few examples of self-powered fluorescence display devices. Here we designed and fabricated a self-powered fluorescence display device based on a fast-charging/recharging battery. The specially designed battery was composed of a Prussian blue (PB) cathode and a magnesium metal anode with a high theoretical redox potential difference (similar to 2.8 V). Moreover, smartly adding a trace amount of NaClO in the electrolyte could realize oxidizing PW to PB similar to 480 times faster than when oxidizing without NaClO, leading to the fast self-charging and high power density (maximum power density of 13.34 mW cm(-2), about two to three orders of magnitude larger than previous bio-fuel cells) of the Mg/PB battery. Most importantly, PB was used as not only the cathodic catalyst but also as an electrochromic material, making it possible to construct a self-powered and rechargeable electrochromic fluorescence display with only two electrodes. Besides, fluorescent [Ru(bpy)(3)](2+)-doped silica nanoparticles (Ru@ SiO2), were selected as the fluorescence resonance energy transfer (FRET) donor to match PB (FRET acceptor). To the best of our knowledge, we demonstrated a self-powered and rechargeable electrochromic fluorescence display with only two electrodes for the first time.