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Development of a novel capillary array photocatalytic reactor and application for degradation of azo dye

机译:新型毛细管阵列光催化反应器的研制及其在偶氮染料降解中的应用

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摘要

A novel capillary array photocatalytic reactor (CAPCR) was developed and the photocatalytic performance towards degradation of azo dye, methyl orange (MO), as a probe pollutant was systematically studied. The TiO2 films were prepared using a sol-gel method and the inner wall of the capillaries was overlaid with a gas pressure-operated device. Higher surface area for catalyst coating per unit reactor volume was obtained in the CAPCR, and an increase in contact between target compounds and photocatalyst. There improvement allowed for much more specific reactor capacity. The TiO2 films were characterized by field emission scanning electron microscopy. X-ray diffraction, and UV-vis absorbance spectra. The optimized experimental conditions for MO degradation in CAPCR were investigated. The CAPCR showed better removal efficiency for MO degradation than that in a conventional batch reactor with P-25 TiO2 powder and TiO2 film immobilized onto a quartz tube.
机译:开发了一种新型的毛细管阵列光催化反应器(CAPCR),并系统研究了作为探针污染物的偶氮染料甲基橙(MO)的光催化性能。使用溶胶-凝胶法制备TiO 2膜,并且用气压操作装置覆盖毛细管的内壁。在CAPCR中,每单位反应器体积的催化剂涂层表面积更大,并且目标化合物与光催化剂之间的接触增加。在那里的改进允许更多的特定反应堆容量。 TiO2薄膜通过场发射扫描电子显微镜表征。 X射线衍射和UV-vis吸收光谱。研究了CAPCR中MO降解的最佳实验条件。与将P-25 TiO2粉末和TiO2薄膜固定在石英管上的常规间歇式反应器相比,CAPCR显示出更好的MO降解去除效率。

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