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INORGANIC PARAMETERS AS WATER QUALITY INDICATORS IN ACIDIC GROUNDWATER IN A TROPICAL REGION - BRASILIA-DF (BRAZIL)

机译:热带地区酸性地下水中无机参数作为水质指标-巴西-DF(巴西)

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摘要

In Brazilian Tropical Cerrado Region, reactions related to parental-material breakdown and oxisols genesis strongly affect the groundwater chemical characteristics. These reactions are responsi-We for the low water pH values, the soil charge balance, and the re-equilibrium of dissolved inorganic carbon species. Brasilia, the capital of Brazil, lies in the Distrito Federal, in the central part of the Brazil-ian Cerrado Region and has been experiencing an intense urban development during the last 15 years. Many town-house complexes have been built without proper water supply or wastewater disposal con-ditions. In this work, we discuss the adequacy of traditional ground waters geochemical classification models applied to the most exploited aquifers in DF. Forty groundwater samples were collected and pH, conductivity and total dissolved solids were determined in the field. Na, K, Ca, Mg, Fe, Al, Cu, Cd, Cr Mn e Zn were determined-by Inductively Coupled Plasma Atomic Emission Spectrometry and Atomic Absorption Spectrophotometry. We identify inorganic indicators of human interference on the quality of these waters and also suggest a new mean of interpretation of dissolved inorganic elements based on statistic treatment of multivariate data. It is revealed a particular geochemical feature concerning to the alkali and the earth alkali metals concentrations, and a typical trace-element behaviour, closely related to the human activities and to the geological-bearing material characteristics. For all of the samples supposed to be altered by any kind of human activity, the physico-chemical parameters were lower than the standards established by the water quality legal system.
机译:在巴西的热带塞拉多地区,与亲本物质分解和羟甲酚生成有关的反应强烈影响了地下水的化学特性。这些反应是对低水pH值,土壤电荷平衡以及溶解的无机碳物质的再平衡的响应。巴西首都巴西利亚位于巴西人塞拉多(Cerrado)地区中部的Distrito Federal,在过去的15年中,它一直在经历着激烈的城市发展。在没有适当的供水或废水处理条件的情况下,建造了许多联排别墅。在这项工作中,我们讨论了适用于DF中开采最多的含水层的传统地下水地球化学分类模型的适用性。收集了40个地下水样品,并在现场确定了pH,电导率和总溶解固体。通过电感耦合等离子体原子发射光谱法和原子吸收分光光度法测定Na,K,Ca,Mg,Fe,Al,Cu,Cd,Cr Mn e Zn。我们确定了人类对这些水质的干扰的无机指标,并且根据多变量数据的统计学处理方法,提出了一种新的手段来解释溶解的无机元素。揭示了与碱和地球碱金属浓度有关的特殊地球化学特征,以及与人类活动和含地质物质特征密切相关的典型痕量元素行为。对于所有可能因任何人类活动而改变的样品,其理化参数均低于水质法律体系规定的标准。

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