The Environmental Impact of the Platinum Group Elements (Pt, Pd, Rh) Emitted by the Automobile Catalyst Converters

摘要

The present paper deals with an extensive review of literature concerning the platinum group elements (PGEs), and their impact on the environment. The increased number of cars and vehicles fitted with catalytic converters, has been linked with the wide spread in the environment of the PGEs, i.e. Pt, Pd and Rh. Numerous studies present compelling evidence that the catalytic converters, do not only minimize the pollution caused by the car exhaust fumes, but also they release in the environment particulate matter containing the above noble elements, which accumulate in the soil, and plants, or remain suspended in the air, being transported to large distances. Indeed, the concentration of these noble elements in the soil and plants has increased significantly during the last 10–15 years, especially along the road side of high ways. Assessment of the PGEs health risk was originally based on measuring the body fluid in Pt, Pd and Rh content of occupationally involved people, as well as of the general population. Recent results based on cellular studies show that the PGEs are related to respiratory sensitization, allergic reactions, dermatitis, urticaria, damage of the epithelial lung cells, asthma, rhinoconjuctivitis, lymphocyte proliferation and cytokine release and possibly to cancer. In spite of the progress attained, more work is necessary for an accurate health risk assessment.