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Adsorption of Phosphate by Amino-Functionalized and Co-condensed SBA-15

机译:氨基官能化和共缩合SBA-15对磷酸盐的吸附

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摘要

In this study, the applications of mesoporous materials based on silica, and those with modifications, namely post-synthetic grafting, co-condensation, and pure SBA-15, were investigated for the removal of phosphate from sewage. The mesostructures were confirmed by X-ray dim-action, Brunauer-Emmett-Teller, Fourier transform infrared spectroscopy, and transmission electron microscopy. The absorption of phosphate by the mesoporous adsorbents was examined, using different adsorption models to describe the equilibrium and kinetic data. The maximum adsorption capacities of the mesostructured adsorbents were found to be 69.970, 59.890, and 2.018 mg/g for the co-condensation, post-synthetic grafting, and pure SBA-15, respectively. The kinetic data showed that the adsorption of phosphate onto three different mesostructures followed the pseudo-first-order kinetic model.
机译:在这项研究中,研究了基于二氧化硅的介孔材料以及经过修饰(即合成后接枝,共冷凝和纯SBA-15)的应用,以去除污水中的磷酸盐。介观结构通过X射线暗淡作用,Brunauer-Emmett-Teller,傅立叶变换红外光谱和透射电子显微镜确认。使用不同的吸附模型描述了平衡和动力学数据,研究了介孔吸附剂对磷酸盐的吸收。发现共缩合,合成后接枝和纯SBA-15的介孔结构吸附剂的最大吸附容量分别为69.970、59.890和2.018 mg / g。动力学数据表明,磷酸盐在三种不同介观结构上的吸附遵循伪一级动力学模型。

著录项

  • 来源
    《Water, Air, and Soil Pollution》 |2012年第5期|p.2551-2562|共12页
  • 作者单位

    Water Research Center, Korea Institute of Science and Technology, Hwarangno 14-gil 5, Seongbuk-gu, Seoul 136-791, Republic of Korea;

    Water Research Center, Korea Institute of Science and Technology, Hwarangno 14-gil 5, Seongbuk-gu, Seoul 136-791, Republic of Korea;

    Water Research Center, Korea Institute of Science and Technology, Hwarangno 14-gil 5, Seongbuk-gu, Seoul 136-791, Republic of Korea;

    Department of Chemical and Biological Engineering, Korea University, Seoul 136-701, Republic of Korea;

    Department of Earth and Environmental Sciences, Korea University, Seoul 136-701, Republic of Korea;

    Water Research Center, Korea Institute of Science and Technology, Hwarangno 14-gil 5, Seongbuk-gu, Seoul 136-791, Republic of Korea;

  • 收录信息 美国《科学引文索引》(SCI);美国《工程索引》(EI);
  • 原文格式 PDF
  • 正文语种 eng
  • 中图分类
  • 关键词

    amino-functionalized; co-condensation; grafting; mesoporous silica; phosphate; SBA-15;

    机译:氨基官能化共冷凝嫁接;介孔二氧化硅磷酸盐SBA-15;
  • 入库时间 2022-08-17 13:40:33

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