Biomass waste gasification - Can be the two stage process suitable for tar reduction and power generation?

摘要

A pilot scale gasification unit with novel co-current, updraft arrangement in the first stage and counter current downdraft in the second stage was developed and exploited for studying effects of two stage gas ification in comparison with one stage gasification of biomass (wood pellets) on fuel gas composition and attainable gas purity. Significant producer gas parameters (gas composition, heating value, content of tar compounds, content of inorganic gas impurities) were compared for the two stage and the one stage method of the gasification arrangement with only the upward moving bed (co-current updraft). The main novel features of the gasifier conception include grate-less reactor, upward moving bed of biomass par ticles (e.g. pellets) by means of a screw elevator with changeable rotational speed and gradual expanding diameter of the cylindrical reactor in the part above the upper end of the screw. The gasifier concept and arrangement are considered convenient for thermal power range 100-350 kW_(th). The second stage of the gasifier served mainly for tar compounds destruction/reforming by increased temperature (around 950 ℃) and for gasification reaction of the fuel gas with char. The second stage used additional combus tion of the fuel gas by preheated secondary air for attaining higher temperature and faster gasification of the remaining char from the first stage. The measurements of gas composition and tar compound con tents confirmed superiority of the two stage gasification system, drastic decrease of aromatic compounds with two and higher number of benzene rings by 1-2 orders. On the other hand the two stage gasification (with overall ER = 0.71) led to substantial reduction of gas heating value (LHV = 3.15 MJ/Nm~3), elevation of gas volume and increase of nitrogen content in fuel gas. The increased temperature (>950℃) at the entrance to the char bed caused also substantial decrease of ammonia content in fuel gas. The char with higher content of ash leaving the second stage presented only few mass% of the inlet biomass stream.