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Single-phase and two-phase anaerobic digestion of fruit and vegetable waste: Comparison of start-up, reactor stability and process performance

机译:果蔬废料的单相和两相厌氧消化:启动,反应器稳定性和工艺​​性能的比较

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摘要

Single-phase and two-phase digestion of fruit and vegetable waste were studied to compare reactor startup, reactor stability and performance (methane yield, volatile solids reduction and energy yield). The single-phase reactor (SPR) was a conventional reactor operated at a low loading rate (maximum of 3.5 kg VS/m~3 d), while the two-phase system consisted of an acidification reactor (TPAR) and a methano-genic reactor (TPMR). The TPAR was inoculated with methanogenic sludge similar to the SPR, but was operated with step-wise increase in the loading rate and with total recirculation of reactor solids to convert it into acidification sludge. Before each feeding, part of the sludge from TPAR was centrifuged, the centrifuge liquid (solubilized products) was fed to the TPMR and centrifuged solids were recycled back to the reactor. Single-phase digestion produced a methane yield of 0.45 m~3 CH_4/kg VS fed and VS removal of 83%. The TPAR shifted to acidification mode at an OLR of 10.0 kg VS/m~3 d and then achieved stable performance at 7.0 kg VS/m~3 d and pH 5.5-6.2, with very high substrate solubilization rate and a methane yield of 0.30 m~3 CH_4/kg COD fed. The two-phase process was capable of high VS reduction, but material and energy balance showed that the single-phase process was superior in terms of volumetric methane production and energy yield by 33%. The lower energy yield of the two-phase system was due to the loss of energy during hydrolysis in the TPAR and the deficit in methane production in the TPMR attributed to COD loss due to biomass synthesis and adsorption of hard COD onto the flocs. These results including the complicated operational procedure of the two-phase process and the economic factors suggested that the single-phase process could be the preferred system for FVW.
机译:研究了水果和蔬菜废物的单相和两相消化,以比较反应器的启动,反应器的稳定性和性能(甲烷产量,挥发性固体减少量和能量产量)。单相反应器(SPR)是常规的反应器,在低负载率(最大3.5 kg V​​S / m〜3 d)下运行,而两相系统则由酸化反应器(TPAR)和甲烷反应器组成。反应堆(TPMR)。 TPAR接种了类似于SPR的产甲烷污泥,但在逐步提高装料速率的同时对反应器固体进行了完全再循环,以将其转化为酸化污泥。在每次进料之前,将来自TPAR的部分污泥进行离心分离,然后将离心分离的液体(增溶产物)加入TPMR,然后将离心分离的固体循环回反应器中。单相消化进料的甲烷产量为0.45 m〜3 CH_4 / kg V​​S,VS去除率为83%。 TPAR在10.0 kg V​​S / m〜3 d的OLR下转变为酸化模式,然后在7.0 kg V​​S / m〜3 d和pH 5.5-6.2时获得稳定的性能,底物增溶速率非常高,甲烷产率为0.30喂食m〜3 CH_4 / kg COD。两相过程能够大幅降低VS,但材料和能量平衡表明,单相过程的甲烷产量和能量收率均优于33%。两相系统的较低能量产量是由于TPAR水解过程中的能量损失以及TPMR中甲烷产生的不足,这归因于生物质合成以及硬质COD吸附到絮凝物上导致的COD损失。这些结果包括两相过程的复杂操作程序和经济因素,表明单相过程可能是FVW的首选系统。

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