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Catalytic Activity of Multi-metallic Perovskite-Type Oxide Prepared by the Thermal Decomposition of Heteronuclear Cyano Complex, Sm[Fe x Co1?x (CN)6] · nH2O

机译:异核氰基配合物Sm [Fe x Co1?x (CN)6 ]·nH2 的热分解制备多金属钙钛矿型氧化物的催化活性Ø

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摘要

The perovskite-type SmFe x Co1?x O3 oxides were prepared by the thermal decomposition of heteronuclear cyano complexes, Sm[Fe x Co1?x (CN)6] ? nH2O. XRD studies demonstrated that SmFe x Co1?x O3 catalyst prepared by the thermal decomposition of heteronuclear cyano complex at 1,273 K showed orthorhombic structure in whole range of x. The catalytic activity for CO oxidation was dependent on x in SmFe x Co1?x O3; the maximum activity was obtained for SmFe0.5Co0.5O3.
机译:钙钛矿型SmFe x Co1?x O3 氧化物是通过异核氰基配合物Sm [Fe x Co1?x ( CN)6 ]吗? nH2 O。 XRD研究表明,异核氰基配合物在1273K条件下热分解制备的SmFe x α1x O3 催化剂在x的整个范围内呈正交晶系结构。 CO氧化的催化活性取决于SmFe x Co1?x O3 中的x。 SmFe0.5 Co0.5 O3 的最大活性。

著录项

  • 来源
    《Topics in Catalysis》 |2009年第7期|823-827|共5页
  • 作者单位

    Department of Materials Science and Biotechnology Graduate School of Science and Engineering Ehime University Matsuyama 790-8577 Japan;

    Department of Materials Science and Biotechnology Graduate School of Science and Engineering Ehime University Matsuyama 790-8577 Japan;

    Department of Materials Science and Biotechnology Graduate School of Science and Engineering Ehime University Matsuyama 790-8577 Japan;

    Department of Materials Science and Biotechnology Graduate School of Science and Engineering Ehime University Matsuyama 790-8577 Japan;

    Department of Materials Science and Biotechnology Graduate School of Science and Engineering Ehime University Matsuyama 790-8577 Japan;

    Department of Materials Science and Biotechnology Graduate School of Science and Engineering Ehime University Matsuyama 790-8577 Japan;

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  • 原文格式 PDF
  • 正文语种 eng
  • 中图分类
  • 关键词

    Perovskite-type oxide; SmFeO3; SmCoO3; Catalytic activity; CO oxidation; Synergistic effect;

    机译:钙钛矿型氧化物;SmFeO3;SmCoO3;催化活性;CO氧化;协同效应;

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