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Circular arrays of polymer-based miniature rectilinear ion traps

机译:基于聚合物的微型直线离子阱的圆形阵列

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摘要

The design and operation of an annular array of parallel, miniature rectilinear ion traps (RITs) isndiscussed. Stereolithography apparatus (SLA), a previously validated method for ion trap fabrication,nwas applied here to construct an array of mass analyzers and their mounting hardware. Two versions ofnthe array were tested, using either six or twelve stretched RITs (x0 ?1.66 mm, y0 ?1.33 mm, z ?16.66nmm) mounted in parallel about the circumference of a circle with the interior and exterior x-electrodenplanes oriented tangential to the inner and outer annulus rings, respectively. The arrangement of the ionntraps is such that the ions are radially ejected just above the throat of a centrally located electronnmultiplier detector into which they are accelerated. The mass analyzer array was mounted in a customnvacuum manifold. The resolution, mass-to-charge ratio (m/z) range, and MS/MS capabilities werentested using electrospray ionization (ESI). The devices were tested in two configurations: (i) separatenion sources for each trap, and (ii) a single ion source for the entire array.
机译:讨论了并联的微型直线离子阱(RIT)的环形阵列的设计和操作。立体光刻设备(SLA)是一种先前验证的离子阱制造方法,在这里被用于构建质量分析仪及其安装硬件的阵列。测试了两个版本的阵列,使用了六个或十二个拉伸的RIT(x0≤1.66mm,y0≤1.33mm,z≤16.66nmm),这些RIT围绕一个圆的圆周平行安装,其内部和外部x电极的切向与内环和外环。离子阱的布置使得离子被径向喷射到正好位于居中位置的电子倍增检测器的喉咙上方,离子被加速进入其中。质量分析仪阵列安装在定制真空歧管中。使用电喷雾电离(ESI)对分辨率,质荷比(m / z)范围和MS / MS功能进行了测试。对设备进行了两种配置的测试:(i)每个阱的分离离子源,以及(ii)整个阵列的单个离子源。

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  • 来源
    《The Analyst 》 |2009年第7期| p.1338-1347| 共10页
  • 作者单位

    aDepartment of Chemistry, Purdue University, West Lafayette, IN 47907,USA. E-mail: cooks@purdue.edu, Fax: +1-765-494-9421, Tel: +1-765-494-5263bSchool of Electrical & Computer Engineering, Purdue University, WestLafayette, IN 47907, USAcWeldon School of Biomedical Engineering, Purdue University, WestLafayette, IN 47907, USA† Electronic supplementary information (ESI) available: effects ofvarying sprayer position and orientation on the performance of theversion 2 RIT array. See DOI: 10.1039/b822140e‡ Current address: Griffin Analytical Technologies, LLC, WestLafayette, IN 47906, USA.,;

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