Hydrothermal Synthesis and Crystal Structure of a New Bisupporting Metal-Oxygen Cluster with Bicapped Pseudo-Keggin Structure: [CuII{Cl0.5Cl(phen)}]2{[PMoV 6MoVI 6O40(VIVO)2][CuII(phen)2]2}?·2H2O (phen = 1,10-Phenathroline)

Dong-Bin Dang; Ya-Nan Jin

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Hydrothermal Synthesis and Crystal Structure of a New Bisupporting Metal-Oxygen Cluster with Bicapped Pseudo-Keggin Structure: [CuII{Cl_0.5Cl(phen)}]₂{[PMoV ₆MoVI ₆O₄₀(VIVO)₂][CuII(phen)₂]₂}?·2H₂O (phen = 1,10-Phenathroline)

机译：[Cu II {Cl _{0.5 Cl（phen）}] _{2的带假位的双支撑金属氧簇的水热合成和晶体结构 {[PMo V _{6 Mo VI _{6 O _{40 （ V IV O）_{2 ] [Cu II （phen）_{2 ] _{2 }？·2H _{2 O（苯酚= 1,10-菲咯啉）}}}}}}}}}

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A new bisupporting metal-oxygen cluster with bicapped pseudo-Keggin compound [CuII{Cl_0.5Cl(phen)}]₂ {[PMoV ₆MoVI ₆O₄₀(VIVO)₂][CuII(phen)₂]₂}?·2H₂O (phen = 1,10-phenathroline) has been synthesized by hydrothermal method and characterized by elemental analysis, IR spectroscopy, TGA, XRPD, and single-crystal X-ray diffraction. The polyoxoanion consists of a bicapped vanadium Keggin polyoxoanion and two {[Cu(phen)]₂}2+ subunits producing bisupporting bicapped Keggin-polyoxometalate structure. The isolated dinuclear unit [CuII{Cl_0.5Cl(phen)}₂]+ acts as the countercation in title compound. In the crystal structure ?? a?? ?? stacking interactions, multiform Ca??H?·?·?·O and Oa??H?·?·?·O hydrogen bonds lead to a three-dimensional network.View full textDownload full textKeywordscrystal structure, hydrothermal synthesis, polyoxometalates, pseudo-KegginRelated var addthis_config = { ui_cobrand: "Taylor & Francis Online", services_compact: "citeulike,netvibes,twitter,technorati,delicious,linkedin,facebook,stumbleupon,digg,google,more", pubid: "ra-4dff56cd6bb1830b" }; Add to shortlist Link Permalink http://dx.doi.org/10.1080/15533174.2010.522538

机译：一个新的带有双位假拟Keggin化合物[Cu II {Cl _{0.5 Cl（phen）}] _{2 {[PMo V _{6 Mo VI _{6 O _{40 （V IV O）_{2 ] [Cu II （phen）_{2 ] _{2 }？·2H _{通过水热法合成了2 O（phen = 1,10-phenathroline），并通过元素分析，红外光谱，TGA，XRPD和单晶X射线衍射进行了表征。聚氧阴离子由一个二位的钒Keggin聚氧阴离子和两个{[Cu（phen）] _{2 } 2 + 亚基组成，产生双支撑的二位的Keggin-聚氧金属酸盐结构。分离出的双核单元[Cu II {Cl _{0.5 Cl（phen）} _{2 ] + 充当抗衡阳离子在标题化合物中。在晶体结构上一个？？ ??堆积相互作用，多形式的Ca ?? H？·？·？·O和Oa ?? H？·？·？·O氢键形成一个三维网络。查看全文下载全文关键词晶体结构，水热合成，多金属氧酸盐，假-KegginRelated var addthis_config = {ui_cobrand：“泰勒和弗朗西斯在线”，servicescompact：“ citeulike，netvibes，twitter，technorati，delicious，linkedin，facebook，stumbleupon，digg，google，更多”，发布：“ ra-4dff56cd6bb1830b”};添加到候选列表链接永久链接http://dx.doi.org/10.1080/15533174.2010.522538}}}}}}}}}}}}

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《Synthesis and Reactivity in Inorganic, Metal-Organic, and Nano-Metal Chemistry》 |2010年第10期|748-753|共6页
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Dong-Bin Dang; Ya-Nan Jin;
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1. Hydrothermal synthesis and crystal structure of a new bisupporting metal-oxygen cluster with bicapped pseudo-keggin structure: [Cu ~(II){Cl_(0.5)Cl(phen)}]_2{[PMo~V_6Mo~(VI)_6O_(40)(V~(IV)O) _2][Cu~(II)(phen)_2]_2}·2H _2O (phen = 1,10-Phenathroline) [J] . Dang D.-B., Fan Y.-H., Bai Y., Synthesis and reactivity in inorganic, metal-organic, and nano-metal chemistry . 2010,第8a10期

机译：[Cu〜（II）{Cl_（0.5）Cl（phen）}] _ 2 {[PMo〜V_6Mo〜（VI）_6O_（40））（V〜（IV）O）_2] [Cu〜（II）（phen）_2] _2}·2H _2O（phen = 1,10-Phenathroline）
2. Hydrothermal syntheses, crystal structures and magnetic properties of two inorganic-organic hybrid materials: [{Cu(phen)}(2)((VO2)-O-V)(2)(VO2)-O-IV(H2O)(PO4)(2)] and [V4O7(2,2 '-bpy)(2)(HPO4)(2)] (phen=1,10-phenathroline, bpy = bipyridine) [J] . Zhang XM., Wu HS., Gao S., International Journal of Quantum Chemistry . 2003,第1期

机译：两种无机-有机杂化材料的水热合成，晶体结构和磁性能：[{Cu（phen）}（2）（（VO2）-OV）（2）（VO2）-O-IV（H2O）（PO4）（ 2）]和[V4O7（2,2'-bpy）（2）（HPO4）（2）]（phen = 1,10-phenathroline，bpy =联吡啶）
3. Hydrothermal synthesis and crystal structure of two hetero-transition metal polymers: [Co(1,10-phen)(2)(V2O4)(O3PCH2CH2CH2PO3)](n) and [{Co(1,10-phen)(2)}(2)(V4O10)(O3PCH2CH2CH2CH2PO3)(2H(2)O)](n) [J] . Fu RB., Hu SM., Fu ZY., New Journal of Chemistry . 2003,第2期

机译：两种异质过渡金属聚合物的水热合成和晶体结构：[Co（1,10-phen）（2）（V2O4）（O3PCH2CH2CH2PO3）]（n）和[{Co（1,10-phen）（2）} （2）（V4O10）（O3PCH2CH2CH2CH2PO3）（2H（2）O）] [n）
4. Synthesis and Crystal Structure of 3-D Complex Cr(phen)(C2O4)3Mn(phen)2(H2O)22ClO4·14H2O [C] . International symposium on solid state chemistry in China amp; 8th Chinese national conference on solid state chemistry and inorganic synthesis : Book of abstracts . 2002

机译：3-D络合物Cr（phen）（C2O4） 3 Mn（phen）2（H2O）2 2ClO4·14H2O的合成及晶体结构
5. Organometallic photonucleases. I. DNA cleavage by the photolysis of cyclopentadienyl metal complexes: Mechanistic studies and sequence selectivity of strand scission by CpW(CO)3CH3. II. Footprinting of chromatin structure and chromatin remodeling by SWI/SNF utilizing CpW(CO)3CH3. III. Dual mechanisms of DNA damage by MoX(eta3-allyl)(CO)3(phen) complexes. [D] . Downs, Jennifer. 2005

机译：有机金属光核酸酶。 I.通过环戊二烯基金属配合物的光解来切割DNA：通过CpW（CO）3CH3进行断裂的机理研究和序列选择性。二。 SWI / SNF利用CpW（CO）3CH3进行染色质结构足迹测定和染色质重塑。三， MoX（eta3-烯丙基）（CO）3（phen）复合物对DNA的双重破坏机制。
6. Synthesis and Biological Activity of Manganese (II) Complexes of Phthalic and Isophthalic Acid: X-Ray Crystal Structures of Mn(ph)(Phen)2(H2O)· 4H2O Mn(Phen)2(H2O)22(Isoph)2(Phen)· 12H2O and {Mn(Isoph)(bipy)4· 2.75biby}n(phH2 = Phthalic Acid; isoph = Isophthalic Acid; phen = 110-Phenanthroline; bipy = 22-Bipyridine) [O] . Michael Devereux, Malachy McCann, Vanessa Leon, 2000

机译：邻苯二甲酸和间苯二甲酸锰（II）配合物的合成和生物活性：Mn（ph）（Phen）2（H2O）·4H2OMn（Phen）2（H2O）2 2的X射线晶体结构（Isoph）2（Phen）·12H2O和{Mn（Isoph）（bipy） 4·2.75biby} n（phH2 =邻苯二甲酸; isoph =间苯二甲酸; phen = 110-邻菲咯啉; bipy = 22 -联吡啶）
7. Synthesis and Biological Activity of Manganese (II) Complexes of Phthalic and Isophthalic Acid: X-Ray Crystal Structures of [Mn(ph)(Phen)2(H2O)]· 4H2O, [Mn(Phen)2(H2O)2]2(Isoph)2(Phen)· 12H2O and {[Mn(Isoph)(bipy)]4· 2.75biby}n(phH2 = Phthalic Acid; isoph = Isophthalic Acid; phen = 1,10-Phenanthroline; bipy = 2,2-Bipyridine) [O] . Devereux, Michael, McCann, Malachy, Leon, Vanessa, 2000

机译：邻苯二甲酸和间苯二甲酸锰（II）配合物的合成和生物活性：[Mn（ph）（Phen）2（H2O）]·4H2O，[Mn（Phen）2（H2O）2] 2的X射线晶体结构（Isoph）2（Phen）·12H2O和{[Mn（Isoph）（bipy）] 4·2.75biby} n（phH2 =邻苯二甲酸; isoph =间苯二甲酸; phen = 1,10-邻菲咯啉; bipy = 2,2 -联吡啶）
8. Synthesis of Tetranuclear Mixed-Metal Clusters via the Reaction of Co(CO)4- with Closed Metal Carbonyl Trimers. Crystal and Molecular Structure of (Ph3P)2NCoRu3(CO)13 [R] . Steinhardt, P. C., Gladfelter, W. L., Harley, A. D., 1979

机译：Co（CO）4-与闭合金属羰基三聚体反应合成四核混合金属团簇。（ph3p）2NCoRu3（CO）13的晶体和分子结构

Hydrothermal Synthesis and Crystal Structure of a New Bisupporting Metal-Oxygen Cluster with Bicapped Pseudo-Keggin Structure: [CuII{Cl0.5Cl(phen)}]2{[PMoV 6MoVI 6O40(VIVO)2][CuII(phen)2]2}?·2H2O (phen = 1,10-Phenathroline)

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Hydrothermal Synthesis and Crystal Structure of a New Bisupporting Metal-Oxygen Cluster with Bicapped Pseudo-Keggin Structure: [CuII{Cl_0.5Cl(phen)}]₂{[PMoV ₆MoVI ₆O₄₀(VIVO)₂][CuII(phen)₂]₂}?·2H₂O (phen = 1,10-Phenathroline)