A New 5-Connected Cu(II) Complex with 5-Bromoisophthalic Acid: Synthesis, Crystal Structure, and Properties

摘要

A new coordination polymer, {[Cu(Brip)(1,4-btb)_1.5]?·2H₂O}_n, (H₂Brip = 5-bromoisophthalic acid, 1,4-btb = 1,4-bis(triazol) butane) was prepared under hydrothermal condition by the reactions of Cu(II) acetate with H₂Brip and 1,4-btb. The title complex was determined by single-crystal X-ray diffraction analysis and further characterized by elemental analysis and IR spectroscopy. Complex 1 has a 3D network extended by both H₂Brip and 1,4-btb ligands that employ the same bis-monodentate bridging coordination modes. From the view of topology, the structure of 1 could be described as a 5-connected (44?·66)-nov net. Two of such nets penetrate with each other to generate a 2-fold interpenetrating 3D network. In addition, the thermal stability of the title complex was briefly investigated.View full textDownload full textKeywords1,4-bis(triazol) butane, 5-bromoisophthalic acid, 5-connected Cu(II) complex, crystal structureRelated var addthis_config = { ui_cobrand: "Taylor & Francis Online", services_compact: "citeulike,netvibes,twitter,technorati,delicious,linkedin,facebook,stumbleupon,digg,google,more", pubid: "ra-4dff56cd6bb1830b" }; Add to shortlist Link Permalink http://dx.doi.org/10.1080/15533174.2011.568450