Synthesis, Characterization, and Crystal Structures of Two Oxidomolybdenum(VI) Complexes With Hydrazones Derived from 3-Hydroxy-2-naphthoic Hydrazide

摘要

Two mononuclear oxidomolybdenum(VI) complexes, [MoO₂(L1)(CH₃OH)]?·CH₃OH (1) and [MoO₂(L2)(CH₃OH)] (2) (H₂L1 = 3-hydroxynaphthalene-2-carboxylic acid (1-methyl-3-oxo-butylidene)hydrazide, H₂L2 = 3-hydroxynaphthalene-2-carboxylic acid [1-(5-chloro-2-hydroxyphenyl)methylidene]hydrazide), were synthesized and characterized by elemental analysis, IR spectra, and single crystal X-ray diffraction. The Mo atom in each of the complexes is six-coordinated by the NNO donor atoms of the hydrazone ligand, one methanol O atom, and two oxo O atoms, forming an octahedral geometry.View full textDownload full textKeywordscrystal structure, hydrazone, molybdenum complex, synthesisRelated var addthis_config = { ui_cobrand: "Taylor & Francis Online", services_compact: "citeulike,netvibes,twitter,technorati,delicious,linkedin,facebook,stumbleupon,digg,google,more", pubid: "ra-4dff56cd6bb1830b" }; Add to shortlist Link Permalink http://dx.doi.org/10.1080/15533174.2012.684229