Preparation and Adsorption Properties of the Graphene Modified by Magnetic Nanoparticles

摘要

In this work, we used the modified Hummers method to synthesize graphene oxide, and the redox reaction of FeCl3 center dot 6H(2)O with the carboxyl group on the surface of acidified graphene was carried out to prepare magnetic nanoparticles modified on the surface of graphene (magnetic graphene nanocomposite). X-ray diffraction (XRD), Scanning Electron Microscope (SEM), Transmission Electron Microscope (TEM), Vibrating Sample Magnetometer (VSM) and Brunauer-EmmettTeller measurement (BET) analyses were used to characterize the nanocomposite properties. SEM and TEM images of the nanocomposite show that the magnetic nanoparticles are distributed on both sides of the graphene, and the magnetic nanoparticles diameter is between 100 and 150 nm. The XRD pattern indicates that the magnetic nanoparticles are Fe3O4 nanoparticles. Based on the VSM, the nanocomposite exhibits a saturation magnetization value of 14.94 emu.g(-1). By BET measurement, the specific surface area of the nanocomposite is 26.54 m(2).g(-1), and the surface of the nanocomposite is highly porous. In the experiment of dyes adsorption, the adsorption efficiency in the solution was close to 100%. It can be applied in biomedical and environmental fields such as water purification owing to its high surface, magnetic attraction properties and good adsorption efficiency.