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Germanium Recovery using Catechol Complexation and Permeation through an Anion-Exchange Membrane

机译:使用邻苯二酚络合和通过阴离子交换膜渗透回收锗

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摘要

Germanium in solution was recovered on an anion-exchange membrane after complexation with 3-methylcatechol. The complex was transferred to the anion-exchange membrane by convection, which meant diffusion was not the rate-determining step as in conventional resin recovery. In batch mode, the optimum solution pH was 8, and at this pH the method was selective for germanium against silicate ion. In continuous mode at pH 11.0 and 2.0, the germanium ion was selectively adsorbed as a complex ion in the membrane. This system could be applied to hydrometallurgy processes for the recovery of germanium.View full textDownload full textKeywordsanion-exchange membrane, catechol, convection, germanium, hydrometallurgyRelated var addthis_config = { ui_cobrand: "Taylor & Francis Online", services_compact: "citeulike,netvibes,twitter,technorati,delicious,linkedin,facebook,stumbleupon,digg,google,more", pubid: "ra-4dff56cd6bb1830b" }; Add to shortlist Link Permalink http://dx.doi.org/10.1080/01496395.2011.613440
机译:与3-甲基邻苯二酚络合后,在阴离子交换膜上回收溶液中的锗。通过对流将络合物转移到阴离子交换膜上,这意味着扩散不是常规树脂回收中决定速率的步骤。在分批模式下,最佳溶液pH为8,在此pH下,该方法对锗对硅酸根离子具有选择性。在pH 11.0和2.0的连续模式下,锗离子作为络合物离子选择性吸附在膜中。该系统可应用于湿法冶金过程中的锗回收。 twitter,technorati,美味,linkedin,facebook,stumbleupon,digg,google,更多“,发布:” ra-4dff56cd6bb1830b“};添加到候选列表链接永久链接http://dx.doi.org/10.1080/01496395.2011.613440

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