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首页> 外文期刊>Sensors and Actuators >A novel sensitive nonenzymatic glucose sensor based on perovskite LaNi_(0.5)Ti_(0.5)O_3-modified carbon paste electrode
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A novel sensitive nonenzymatic glucose sensor based on perovskite LaNi_(0.5)Ti_(0.5)O_3-modified carbon paste electrode

机译:基于钙钛矿LaNi_(0.5)Ti_(0.5)O_3-修饰的碳糊电极的新型灵敏非酶葡萄糖传感器

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摘要

A novel sensitive nonenzymatic glucose sensor was reported based on perovskite LaNio.5Tio.5O3 (LNT) modified carbon paste electrode (CPE). The surface characterization of the modified electrode and the bare CPE was examined by scanning electron microscopy (SEM). The high electrochemical activity of LNT to electrocatalytic oxidation of glucose in alkaline medium was characterized by cyclic voltammetry and amperometry, and the experimental conditions such as the amount of LNT, the concentration of NaOH and the applied potential were investigated in detail. The glucose sensor was applied to the quantification of glucose with a high sensitivity of 1630.57 μAmM~(-1) cm~(-2) and a low limit of detection of 0.07 μM.The novel glucose sensor also exhibited good reproducibility, long-term stability, as well as high selectivity with no interference from common interfering substances such as ascorbic acid, dopamine and uric acid.
机译:报道了一种基于钙钛矿LaNio0.5Tio0.5O3(LNT)修饰碳糊电极(CPE)的新型灵敏非酶葡萄糖传感器。通过扫描电子显微镜(SEM)检查了改性电极和裸露的CPE的表面特性。用循环伏安法和安培法表征了LNT对碱性介质中葡萄糖的电催化氧化的高电化学活性,并详细研究了LNT的用量,NaOH的浓度和施加的电势等实验条件。该葡萄糖传感器用于葡萄糖的定量分析,灵敏度高达1630.57μAmM〜(-1)cm〜(-2),检测下限为0.07μM,具有良好的重现性,长期性稳定性好,选择性高,不受普通干扰物质如抗坏血酸,多巴胺和尿酸的干扰。

著录项

  • 来源
    《Sensors and Actuators》 |2010年第1期|p.65-70|共6页
  • 作者单位

    College of Sciences. Shanghai University, Shanghai 200444, PR China;

    Shanghai Key Laboratory of Modern Metallurgy & Materials Processing, School of Materials Science and Engineering, Shanghai University, Shanghai 200444, PR China;

    College of Sciences. Shanghai University, Shanghai 200444, PR China;

    College of Sciences. Shanghai University, Shanghai 200444, PR China,Shanghai Key Laboratory of Modern Metallurgy & Materials Processing, School of Materials Science and Engineering, Shanghai University, Shanghai 200444, PR China;

    College of Sciences. Shanghai University, Shanghai 200444, PR China;

    College of Sciences. Shanghai University, Shanghai 200444, PR China;

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  • 原文格式 PDF
  • 正文语种 eng
  • 中图分类
  • 关键词

    nonenzymatic sensor; glucose; perovskite; amperometry;

    机译:非酶传感器葡萄糖;钙钛矿安培法;

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