Development of a micro-flame ionization detector using a diffusion flame

摘要

A micro-flame ionization detector (micro-FID) design is presented that is targeted for use in a portable gas sensor. Our micro-FID is based on a diffusion flame and features a folded flame structure that is more sensitive than a counter-flow flame designs. Unlike conventional FIDs that use a premixed or open diffusion flame, an air-hydrogen diffusion flame is employed and tested in an encapsulated structure of Quartz-Macor-Quartz layers. Diffusion flames are generally known to be more controllable and stable than premixed flames, where the stability of the micro-FID plays an important role for portable gas sensors. Various channel designs for oxidant and fuel flows meeting with different angles at the burner cavity are tested to obtain a stable flame and high output sensitivity over methane test samples. To verify the empirically designed microchannel, we simulate the temperature distribution in the microchannel by using computational fluid dynamics (CFD) software. To gauge the sensitivity of the device, the collected electric charges per mole (C/mol) is calculated and taken as a reference value of ionization efficiency. The result of the folded flame design is 1.959 × 10~(-2) C/mol for methane that is about 34 times higher than the result using a counter-flow flame, which is 5.73 × 10~(-4) C/mol for methane, while one of the commercial macro FIDs' is 10~(-1) C/mol. This result shows that the micro-FID using the folded flame structure has higher ionization efficiency with less leakage of the analytes than of the classical counter-flow flame design.