New Zinc functionalized metal organic Framework for selective sensing of chromate ion

摘要

A modified metal organic framework have been prepared by the solvothermal process of 2-(4-carboxyphenyl}-l, 3-dioxoisoindoline-5-carboxylic acid with Zn(OAc)_2.2H_2O. The framework has a PtS - type net. The obtained porous material has been characterized by X-ray diffraction, Scanning electron microscopy, UV-vis spectroscopy, FTIR spectroscopy and BET surface area analysis. The BET surface area was 757m~2/g~(-1). The synthesized MOF exhibits reasonably good fluorescence characteristics. The luminescent studies indicates that the obtained Zn-MOF could be an efficient material for selectively sensing anion especially CrO_4~(2-). The mechanism of sensing is also studied in detail. The Zn-MOF senses the anion without altering its structural integrity. This post-synthesis route can be used for synthesis of isomorphous metal-organic frameworks that cannot be obtained by direct synthesis.