Adsorption property and mechanism of polyacrylate-divinylbenzene microspheres for removal of trace organic micropollutants from water

摘要

In this study, polyacrylate-divinylbenzene (PADVB) microspheres were facilely prepared via the precipitation polymerization method, and the microspheres were used as an efficient adsorbent for the removal of trace level organic micropollutants (OMPs) from environmental waters. Preparation conditions of PADVB microspheres were optimized, and the characterizations of the microspheres were performed using a scanning electron microscope (SEM), Fourier transform infrared spectroscopy (FT-IR), and N_2 adsorption/desorption isotherms. The micro-spheres had broad-spectrum adsorption ability for various organic micropollutants containing hydroxy, amidogen, aromatic or heteroaromatic ring in their chemical structure, such as atrazine, 2,4 dichlorophenol, 2,4 dibromophenol, 2,6 dichlorophenol, sulfamethoxazole, estradiol, and bisphenol A. Besides, the effects of initial concentration, initial pH value, adsorption time, and the type of adsorbates on the adsorption performance were investigated systematically. PADVB microspheres could be used for removing trace OMPs from environmental water. Monolayer and homogeneous sorption process occurred on the surface of PADVB microspheres through chemisorption mechanisms. The X-ray photoelectron spectroscopy (XPS) and FT-IR spectrum of PADVB microspheres before and after adsorption proved that the OMPs adsorption onto PADVB microspheres was mainly due to the formation of the hydrogen bond and π-π electron-donor-acceptor (EDA) interactions. Besides, PADVB microspheres can be recovered for reuse via (low-pressure) microfiltration and could be regenerated sufficiently by using 80% (v/v) ethanol.