Ferrous-activated sodium percarbonate pre-oxidation for membrane fouling control during ultrafiltration of algae-laden water

摘要

Membrane technology has been shown to be promising for the treatment of algae-laden water, but membrane fouling is still an obstacle influencing the purification efficiency and effluent quality. To mitigate ultrafiltration membrane fouling during Microcystis aeruginosa-laden water treatment, a strategy of sodium percarbonate pre-oxidation activated with ferrous ion (Fe~(2+)/SPC) was put forward in this study. Due to the synergistic effect of Fe~(2+) and SPC, this process was significantly more efficient with the tetminal specific flux increased from 0.097 to 0397, and the reversible fouling resistance reduced by approximately 80%. It was also found that subsequent sedimentation followed by Fe~(2+)/SPC could further improve the fouling control efficiency. The model fitting results indicated that Fe~(2+)/SPC pre-oxidation delayed the transition from standard blocking to cake filtration. Extracellular organic matter and algal cells were extracted from algal foulants to explore the contribution of each component, and the fouling control efficiencies were systematically studied. The characteristics of the algal foulants were determined with fluorescence excitation-emission matrix spectrum, and the results suggested that macromolecular proteinaceous substances were more efficiently removed by Fe~(2+)/SPC, in comparison with humic-like matters. The alleviation of membrane fouling was also verified by the characterization methods of scanning electron microscopy and attenuated total reflection-Fourier infrared spectroscopy. Overall, the proposed strategy of Fe~(2+)/SPC has an application prospect for membrane fouling control in algal-laden water treatment.