Polycyclic aromatic hydrocarbons in the soils of the Yangtze River Delta Urban Agglomeration, China: Influence of land cover types and urbanization

摘要

With the development of urbanization, urban areas have become the main sources and sinks of polycyclic aromatic hydrocarbons (PAHs).The effects of human activities on the behaviors of PAHs in urban agglomerations have attracted significant attention. We collected soil samples (n = 330) to investigate the distribution, composition, and sources of 16 PAHs in the Yangtze River Delta Urban Agglomeration using the land resolution of 24 km × 24 km. The concentrations of ∑_(16)PAHs ranged from 21 to 2034 ng/g, with a median value of 124 ± 338 ng/g. The concentrations of PAHs were highest in impervious surfaces (350 ± 352 ng/g), followed by grassland (259 ± 322 ng/g), cropland (254 ± 341 ng/g), forest (190 ± 303 ng/g), and water (68 ± 34 ng/g). PAHs were dominated by medium-molecular-weight components (4 rings PAHs), followed by PAHs with high-molecular-weight (5-6 rings PAHs) and low-molecular-weight (2-3 rings PAHs) components. Fluoranthene, benzo[a]anthracene and chrysene are three major pollutants in YRDUA. A positive matrix factorization model indicated that fossil fuel combustion, coal combustion and volatilization, vehicle emission, and biomass burning were the main sources of PAHs, contributing 36%, 29%, 22%. and 12% of PAH sources, respectively. Urbanization parameters were positively correlated with PAH concentrations. A land use regression (LUR) model integrated with urbanization parameters showed evidence of the strong relationship between measured PAHs and predicted PAHs. These findings together highlighted that land cover types and human activities intensively influenced the PAHs pollution in the highly urbanized zones.