Compositions, sources and health risks of ambient volatile organic compounds (VOCs) at a petrochemical industrial park along the Yangtze River

摘要

Petrochemical industry (PI) is an important emission sector of anthropogenic volatile organic compounds (VOCs). The health impacts of VOCs from PI have caused a wide attention by both scientists and publics. In this study, compositions, sources and health risks of VOCs at a typical petrochemical industrial park along the middle reach of Yangtze River were studied. The total VOC concentrations were in the range of 5.59 to 541 ppbv with a mean value of 54.8 ppbv. Alkanes (41.4 ± 15.7%) were the predominant group, followed by alkenes (19.9 ± 18.3%), OVOCs (14.7 ± 9.26%), halo hydrocarbon (11.2 ± 6.42%), aromatics (8.17 ± 5.08%), and acetylene (4.54 ± 2.80%). Compound-specific health tisk results showed that acrolein and 1,3-butadiene had the highest non-carcinogenic risk (expressed by hazard ratio, HR: 22.8) and carcinogenic risk (expressed by lifetime cancer risk, LCR: 6.7 × 10~(-3)), respectively. Positive matrix factorization (PMF) model identified four VOC sources including fuel evaporation, industrial sources, ethylene industry and regional background with the average contributions of 35.6%, 12.0%, 26.5% and 25.9%, respectively. The receptor-originated approach combining the PMF model and conventional methods (HR and LCR) was used to assess the source-specific health risks. The non-cancer risks of four VOC sources were above safe level with regional background contributing most (38.3% or 4.91) to HR.The cancer risks of the four sources were below the tolerable level (<10~(-4)) and regional background also contributed most, with relative contribution of 58.4% (or 10~(-4.22)) to LCR. Our results are conductive to the formulation of countermeasures to reduce human exposure to ambient VOCs at petrochemical industrial parks in China.