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Evaluation of trans-resveratrol level in grape wine using laser-induced porous graphene-based electrochemical sensor

机译:使用激光诱导的多孔石墨烯基电化学传感器评估葡萄酒中的白藜芦醇含量

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摘要

trans-Resveratrol (TRA), is one of the indicators to evaluate the quality of red wines. In this study, a novel flexible electrochemical sensor using direct laser-induced graphene (LIG) technique that transforms the commercial Kapton tape into three-dimensional (3D) porous graphene was developed for sensitive detection of TRA molecules in red wines. For the first time, the strategy of'double layer' (Kapton/polyimide) was employed to obtain the LIG with undamaged shape and excellent electrical properties. The mechanism of heat absorption and dissipation of laser-induced process was investigated in detail. The prepared electrochemical sensor with excellent repeatability, stability, reproducibility, and reliability, appears an excellent linear response within the TRA concentration range from 0.2 to 50 μmol L~(-1) and a low limit of detection (LOD) of 0.16 umol L~(-1). Furthermore, the developed sensor can be applied for the evaluation of TRA level in red wines and grape skins with a satisfactory result. The sensor may be potential in analysis of active compounds in food or environmental samples.
机译:反式白藜芦醇(TRA)是评估红酒质量的指标之一。在这项研究中,开发了一种使用直接激光诱导石墨烯(LIG)技术的新型柔性电化学传感器,该传感器将商业Kapton带转变为三维(3D)多孔石墨烯,用于红酒中TRA分子的灵敏检测。首次采用“双层”(Kapton /聚酰亚胺)策略获得形状未损坏且电性能优异的LIG。详细研究了激光诱导过程的吸热和耗散机理。所制备的电化学传感器具有良好的重复性,稳定性,可重复性和可靠性,在TRA浓度范围为0.2至50μmolL〜(-1)时表现出优异的线性响应,并且检测限(LOD)的下限为0.16 umol L〜。 (-1)。此外,开发的传感器可用于评估红酒和葡萄皮中的TRA水平,结果令人满意。该传感器在分析食品或环境样品中的活性化合物方面可能具有潜力。

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