The impact of ship emissions on PM_(2.5) and the deposition of nitrogen and sulfur in Yangtze River Delta, China

摘要

Ship emissions contribute significantly to the deterioration of air quality, while their impacts on ambient PM2.5 and depositions have not been comprehensively evaluated. This is especially true for China because it has a long coastline, busy shipping routes and many large ports. To fill this gap, this study applied the SMOKE/WRF/CMAQmodeling system to quantifying the impacts of ships on PM2.5 compositions, annual and seasonal contribution to PM2.5 as well as the wet and dry deposition of nitrogen and sulfur compounds over the land areas in YRD region for 2014. The results showed that 4.0% of annual PM2.5 concentrations over the land areas could be explained by ship emissions and the largest contribution could reach up to 35.0% in port areas. Temporally, the contribution to PM2.5 exhibited an obviously seasonal variation. The highest contribution was predicted in autumn (62%), followed by summer (5.4%), spring (3.6%) and winter (12%) for the land areas. Spatially, the contribution reached up to 13.6% along the coastline and dropped to 2.1% 300 km inland. As for the impacts on PM(2.5 )components, the primary components were relatively small and increased mainly along the shipping routes and the Yangtze River, whereas the secondary components played a more important role in both water and land areas. The sulfur deposition due to ship emissions was occurred generally along the shipping routes and was dominated by the dry SO2 deposition. The nitrogen depositions, on the contrary, was observed not only along the shipping routes but also extend to wide land areas. Further investigation revealed that ship emissions have caused an evident increase of dry nitrogen deposition in NO2 and HNO3, while a slight decrease in NH3 over YRD region.These results indicated that comprehensive regulations of ship emissions arc required considering their adverse effects on the ambient concentration of PM(2.5 )and the deposition of sulfur and nitrogen. (C) 2018 Elsevier B.V. All rights reserved.