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A Generalized Approach to the Synthesis of Mesoporous Mixed Metal Oxides Using the Cation-Anion Double Hydrolysis Method

机译:阳离子-阴离子双水解法合成介孔混合金属氧化物的通用方法

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摘要

A series of mesoporous mixed metal oxides were prepared by using a cation-anion double hydrolysis method, which was demonstrated to be a generalized approach for the synthesis of mesoporous mixed metal oxides. The mesoporous mixed oxides were characterized by N_2 adsorption, X-ray diffraction, transmission electronic microscopy and energy dispersive X-ray analysis techniques. Results showed that thus obtained mixed metal oxide catalysts possess a high surface area, high loading of active component together with high dispersion, verifying that this approach is advantageous over the conventional wet impregnation method. The prepared mesoporous mixed oxides exhibit a great potential in replacing the traditional catalysts currently used in many important chemical processes.
机译:通过使用阳离子-阴离子双水解法制备了一系列的介孔混合金属氧化物,这被证明是合成介孔混合金属氧化物的通用方法。通过N_2吸附,X射线衍射,透射电子显微镜和能量色散X射线分析技术对介孔混合氧化物进行了表征。结果表明,由此获得的混合金属氧化物催化剂具有高的表面积,高的活性组分负载量以及高的分散性,证明了该方法优于常规的湿法浸渍方法。制备的介孔混合氧化物在取代当前许多重要化学过程中使用的传统催化剂方面显示出巨大潜力。

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  • 来源
    《Science of advanced materials》 |2011年第6期|p.994-1003|共10页
  • 作者单位

    State Key Laboratory for Heavy Oil Processing, PetroChina Key Laboratory of Catalysis, China University of Petroleum, Qingdao, 266555, China,Department of Chemical and Biomolecular Engineering, National University of Singapore, 4 Engineering Drive 4, Singapore 117576;

    Department of Chemical and Biomolecular Engineering, National University of Singapore, 4 Engineering Drive 4, Singapore 117576,Nanoscience and Nanotechnology Initiative, National University of Singapore, Singapore 117576;

    State Key Laboratory for Heavy Oil Processing, PetroChina Key Laboratory of Catalysis, China University of Petroleum, Qingdao, 266555, China;

    Department of Chemical and Biomolecular Engineering, National University of Singapore, 4 Engineering Drive 4, Singapore 117576,Nanoscience and Nanotechnology Initiative, National University of Singapore, Singapore 117576;

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  • 原文格式 PDF
  • 正文语种 eng
  • 中图分类
  • 关键词

    composites; metal oxides; mesoporous materials; catalysis; double hydrolysis;

    机译:复合材料金属氧化物介孔材料催化;双重水解;

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