Characterization and properties of Eu3+-doped CdWO₄ prepared by a hydrothermal method

摘要

Eu3+-doped CdWO₄ was prepared for the first time by a hydrothermal method. The structure, morphology, and luminescence of the Eu3+-doped CdWO₄ were characterized. TEM results revealed that the pure CdWO₄ was a nanorod with a width of about 50 nm. The photoluminescent properties of Eu3+-doped CdWO₄ complexes indicated energy transfer from WO₄ 2− groups to Eu3+ and suggested effective doping of Eu3+ into the lattice of CdWO₄. The photocatalytic activity of CdWO₄ and Eu3+-doped CdWO₄ was investigated by the photodegradation of methyl orange (MO). Eu3+-doped CdWO₄ had enhanced photocatalytic activity in the photodegradation of MO. The hydroxyl radical was detected by the terephthalic acid photoluminescence (TA-PL) method, and the regular change revealed that the hydroxyl radical may be the active species.