Fine Structure and Hyperfine Structure Effects in Unimolecular and Complex-Forming Bimolecular Reactions

摘要

Fine structure and hyperfine structure effects can influence the kinetics of unimolecular and complex-forming bimolecular reactions. The corresponding energetic effects are analyzed in the framework of the statistical adiabatic channel model (SACM). The reactions O + OH → O_2 + H, OH + CO → H + CO_2, C~+ + OH → products, C~+ +NO → products, and NO_2 → O + NO serve as examples.