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Computational analysis of operating temperature, hydrogen flow rate and anode thickness in anode-supported flat-tube solid oxide fuel cells

机译:阳极支撑扁管固体氧化物燃料电池的工作温度,氢气流速和阳极厚度的计算分析

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摘要

Flat-tube solid oxide fuel cells (FT-SOFCs) are advantageous because of their easy sealing, low stack volume and low resistance to current collection. The performance of FT-SOFCs is determined by the electrochemical reaction, which is closely linked to the heat and mass transfer inside the cell. Therefore, both the electrochemical reaction and the transport phenomena are investigated in this study using a numerical approach. Numerical results are evaluated by physical property models, governing equations and electrochemical reaction models. After simulation, the results are compared with experimental data for code validation, and the current density and the temperature are presented as numerical results. The FT-SOFC performance improves with a higher operating temperature due to the activated electrochemical reaction. If the cell support is thickened in order to achieve higher mechanical strength, the mass transfer rate is reduced and the ohmic polarization increases. These phenomena can lower the performance. Increasing the amount of hydrogen provides a higher mass transfer rate; therefore, the FT-SOFC can obtain a higher and a more uniform current density distribution.
机译:扁平管固体氧化物燃料电池(FT-SOFC)具有优势,因为它们易于密封,堆垛体积小且集电电阻低。 FT-SOFC的性能取决于电化学反应,而电化学反应与电池内部的传热和传质紧密相关。因此,本研究使用数值方法研究了电化学反应和迁移现象。通过物理性质模型,控制方程和电化学反应模型评估数值结果。经过仿真后,将结果与实验数据进行比较以进行代码验证,并且将电流密度和温度表示为数值结果。由于活化的电化学反应,FT-SOFC性能在较高的工作温度下得以改善。如果为了获得更高的机械强度而增厚电池支撑件,则传质速率降低并且欧姆极化增加。这些现象会降低性能。氢的增加提供了更高的传质速率。因此,FT-SOFC可以获得更高,更均匀的电流密度分布。

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