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首页> 外文期刊>Rendiconti Lincei >New opportunity to investigate physico-chemical phenomena: time-resolved X-ray and IR concurrent analysis
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New opportunity to investigate physico-chemical phenomena: time-resolved X-ray and IR concurrent analysis

机译:研究物理化学现象的新机会:时间分辨的X射线和IR同时分析

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摘要

The characterization of both collective and individual excitations occurring in condensed matter and biological systems are of great interests for both fundamental and technological researches. New time-resolved and concurrent approaches are required to characterize complex systems where physical–chemical phenomena occur due to the interplay between localized and delocalized electrons, and in particular to characterize systems in non-equilibrium conditions. In this contribution, we present an optical layout that may take advantage of the high brilliance and the naturally wide spectral-distribution of the synchrotron radiation emission covering the range from the IR to the hard X-ray region. Thanks to the brilliance and the power associated to third generation storage rings with a conceptual new beamline design combining an IR and an X-ray beam, it will be possible to investigate dynamical processes with a time resolution down to the sub-millisecond regime, resolving plenty of correlated structural, electronic and vibrational phenomena. To demonstrate the unique advantages of this time-resolved concurrent experimental approach, among the many existing scientific cases, a few interesting but unresolved scientific cases are reviewed and potential applications of the new analytical tool are envisaged.
机译:凝聚态物质和生物系统中发生的集体和个体激发的表征对于基础研究和技术研究都非常重要。需要新的时间分辨和并发方法来表征由于局部电子和离域电子之间的相互作用而发生物理化学现象的复杂系统,尤其是表征非平衡条件下的系统。在这一贡献中,我们提出了一种光学布局,可以利用同步辐射辐射的高亮度和自然宽光谱分布来覆盖从IR到硬X射线区域的范围。借助结合了IR和X射线束的概念性新光束线设计,由于第三代存储环具有出色的亮度和强大的功能,因此有可能研究时间分辨率低至亚毫秒级的动态过程,从而解决许多相关的结构,电子和振动现象。为了证明这种时间分辨并发实验方法的独特优势,在许多现有的科学案例中,回顾了一些有趣但尚未解决的科学案例,并展望了这种新分析工具的潜在应用。

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