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Preparation Of Epoxy-modified Polyethylene By Graft Extrusion And Its Applications To Polyphenylene Sulfide Alloys As A Compatibilizer

机译:接枝挤出制备环氧改性聚乙烯及其在增容聚苯硫合金中的应用

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摘要

Epoxy-modified polyethylene (PE-g-GMA) was successfully synthesized from glycidyl methacrylate (GMA) and low-density polyethylene (LDPE) via the grafting reaction of extrusion. The mechanism of grafting reaction and the rapid determination for the percentage of grafting are also reported. Experimental results demonstrated that the PE-g-GMA is a good compatibilizer in polyphenylene sulfide/poly(ethylene terephthalate) (PPS/PET) as well as PPSylon 6,6/glass fiber alloys and the addition of PE-g-GMA into PPS alloys may effectively improve the mechanical properties of composites.
机译:通过甲基丙烯酸缩水甘油酯(GMA)和低密度聚乙烯(LDPE)的挤出接枝反应成功地合成了环氧改性聚乙烯(PE-g-GMA)。还报道了接枝反应的机理和快速测定接枝百分比的方法。实验结果表明,PE-g-GMA在聚苯硫醚/聚对苯二甲酸乙二醇酯(PPS / PET)以及PPS /尼龙6,6 /玻璃纤维合金中是很好的相容剂,并且添加了PE-g-GMA进入PPS合金可有效改善复合材料的机械性能。

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