REACTIVITY OF IMIDAZOLES IN PULSE AND γ-IRRADIATED LIQUID AND FROZEN SYSTEMS

摘要

The reactivity and decomposition of imidazoles have been studied in methanol, methanol-water and chlorides-methanol-water systems. It has been shown by pulse radiolysis and steady-state experiments that imidazoles are medium reactive towards electrons and rather low reactive towards radicals, particularly in chloride-methanol-water frozen matrices.