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Gasifying agents type at lower temperature effect on bubbling fluidised bed gasification for low rank coal

机译:低温下的气化剂类型对低阶煤鼓泡流化床气化的影响

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Oxygen and steam as gasifying agents are preferred for gasification process compared to air due to the production of higher heating value of syngas and lower contents of diluents. Lower operating temperature is required for low rank coal (LRC) gasification process. This is because, carbon conversion will occur faster with high reactivity of LRC. Ash agglomeration formation is also prevented at lower operating temperature. Hydrodynamics of bubbling fluidisation and gasification process are expected to be affected with different gasifying agents and operating temperature. Computational fluid dynamics (CFD) method was used to select suitable superficial velocity for bubbling fluidised bed (BFB) simulation and explore the effects of different gasifying agents at a lower operating temperature. The model was validated with theoretical values and superficial velocities of three to four times the minimum velocity (3 similar to 4U(mf) ) were selected due to its best uniform bubbling fluidisation. Different gasifying agents will produce different bubbling patterns which relates to the density and viscosity of the gasifying agents. Many and faster moving bubbles were produced when using oxygen and air at 1,073 K while no changes is detected when using steam. This concludes that air and oxygen as gasifying agents give higher effect to the bubbling hydrodynamics compared to selection of steam as gasifying agent.
机译:与气相比,氧气和蒸汽作为气化剂更适合用于气化工艺,因为它会产生更高的合成气热值和更低的稀释剂含量。低等级煤(LRC)气化过程需要较低的操作温度。这是因为,随着LRC的高反应性,碳转化将更快地发生。在较低的工作温度下,也可以防止形成灰块。鼓泡流化和气化过程的流体力学预计会受到不同气化剂和操作温度的影响。计算流体动力学(CFD)方法用于为鼓泡流化床(BFB)模拟选择合适的表观速度,并探索不同气化剂在较低工作温度下的影响。该模型已通过理论值进行了验证,并且由于其最佳的均匀起泡流化作用,因此选择了最低速度的三至四倍(3类似于4U(mf))的表面速度。不同的气化剂将产生与气化剂的密度和粘度有关的不同的鼓泡模式。在1,073 K下使用氧气和空气时,会产生许多且运动更快的气泡,而在使用蒸汽时未检测到变化。得出的结论是,与选择蒸汽作为气化剂相比,空气和氧气作为气化剂对起泡流体力学的影响更大。

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