Organic thermal stabilizers for rigid poly (vinyl chloride). Part XIII: Eugenol (4-allyl-2-methoxy-phenol)

摘要

Eugenol (4-allyl-2-methoxy-phenol) has been examined as a thermal stabilizer and co-stabilizer for rigid PVC in air, at 180℃. Its high stabilizing efficiency is detected by its high thermal stability value (Ts) when compared with some of the common reference stabilizers used industrially such as dibasic lead carbonate, calcium—zinc soap and octyl tin mercaptide. Blending this organic stabilizer with some of the reference stabilizers in different ratios had synergistic effect on both the induction period and the dehydrochlorination rate together with the longer extent of discolouration of PVC stabilized by eugenol as compared with the blank and the samples stabilized with reference commercial stabilizers. A probable mechanism for the stabilizing action of eugenol has been proposed. The stabilizing efficiency is attributed partially to the stabilizer's ability to intervene in the radical chain degradation process of PVC and to the replacement of the labile chlorine atoms on PVC chains by a relatively more stable moiety of the organic stabilizer.