Glycolysis of poly(ethylene terephthalate) (PET) using basic ionic liquids as catalysts

摘要

The glycolysis of poly(ethylene terephthalate) (PET) was studied using several ionic liquids and basic ionic liquids as catalysts. The basic ionic liquid, l-butyl-3-methylimidazolium hydroxyl ([Bmim]0H), exhibits higher catalytic activity for the glycolysis of PET, compared with l-butyl-3-methylimidazolium bicarbonate (|Bmim]HC03), l-butyl-3-methylimidazolium chloride ([BmimjCl) and l-butyl-3-methyl-imidazolium bromide ([Bmim]Br). FT-IR, 'H NMR and DSC were used to confirm the main product of glycolysis was bis(2-hydroxyethyl) terephthalate (BHET) monomer. The influences of experimental parameters, such as the amount of catalyst, glycolysis time, reaction temperature, and dosages of ethylene glycol on the conversion of PET, yield of BHET were investigated. The results showed a strong influence of the mixture evolution of temperature and reaction time on depolymerization of PET. Under the optimum conditions of m(PET):m(EG): 1:10, dosage of [BmimJOH at 0.1 g (5 wt%), reaction temperature 190 ℃ and time 2 h, the conversion of PET and the yield of BHET were 100% and 71.2% respectively. Balance between the polymerization of BHET and depolymerization of PET could be changed when the reaction time was more than 2 h and contents of catalyst and EG were changed.