Cu- and Zn-acetate-containing ionic liquids as catalysts for the glycolysis of poly(ethylene terephthalate)

摘要

The glycolysis of polyethylene terephthalate (PET) was studied using l-butyl-3-methylimidazolium acetate-promoted copper acetate (Cu(OAc)_2-[Bmim][OAc]) and 1-Butyl-3-methylimidazolium acetate-promoted zinc acetate (Zn(OAc)_2-[Bmim][OAc]) as catalysts. The effects of temperature, time, ethylene glycol (EG) amount, PET amount and catalyst dosage on the glycolysis reaction were examined. Under the optimal conditions of 1.0 g of catalyst with 20 g of EG in the presence of 3.0 g of PET at 190 ℃ after 3 h of glycolysis, complete PET conversion was achieved using Cu(OAc)_2-[Bmim][OAc] and Zn(OAc)_2-[Bmim] [OAc], and the yield of bis (2-hydroxyethyl) terephthalate (BHET) reached 53.95% and 45.6%, respectively. The ionic liquid could be reused up to 6 times with no apparent decrease in the PET conversion or BHET yield. The reaction mechanism was proposed. The reaction kinetics for Cu(OAc)_2-[Bmim][OAc] and Zn(OAc)_2-[Bmim][OAc] was first-order with an activation energy of 56.4 kJ mol~(-1) and 53.8 kJ mol~(-1), respectively.