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Comparison of mechanical properties of heat treated beech wood cured under nitrogen or vacuum

机译:氮气或真空下固化的山毛榉木热处理机械性能的比较

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摘要

Heat treated wood has been subjected to increasing interest during the last decade. This non biocidal treatment is an attractive alternative with a low environmental impact to improve decay resistance of low natural durability wood species. Nowadays, several types of heat treatment processes exist. These treatments differ mainly by the nature of the inert atmosphere used to avoid combustion of wood: nitrogen, steam pressure, oil or more recently vacuum. We have shown in a previous study that utilization of vacuum to perform thermal treatment instead of nitrogen allows to reduce considerably degradation of wood polysaccharrides. Indeed, it appears that for a similar 12% mass loss generated by thermal degradation, thermodegradation performed under vacuum allowed to reduce degradation of sugar constitutive of hemicelluloses and formation of recondensation products within the wood structure. These results may be explain by the effect of vacuum allowing removal of volatile degradation products like organic acids, aldehydes and furans limiting therefore acidic degradation of polysaccharides and recondensation of volatile by-products. Decay durability tests, performed against different brown and white rots fungi, have shown no significant differences for vacuum and nitrogen heat treated samples, all presenting an improved decay resistance. According to these results, the aim of this short paper is to report the effect of vacuum versus nitrogen on the mechanical properties of heat treated samples making the assumption that lower degradation of wood polysaccharides during treatment performed under vacuum may reduce the weakening of mechanical properties. For this purpose, modulus of rupture (MOR) and modulus of elasticity (MOE) in bending and Brinell hardness (HB) were determined. Results show that the mechanical properties were lower degraded in the case of wood samples treated under vacuum.
机译:在过去的十年中,热处理过的木材受到越来越多的关注。这种非杀生物的处理方法是一种有吸引力的替代方法,它对环境的影响很小,可以改善低自然耐久性木材的耐腐性。如今,存在几种类型的热处理工艺。这些处理的主要区别在于用于避免木材燃烧的惰性气氛的性质:氮气,蒸汽压,油或最近的真空。我们在先前的研究中表明,利用真空代替氮气进行热处理可以大大减少木材多糖的降解。实际上,对于由热降解产生的类似的12%的质量损失,看来在真空下进行的热降解可以减少半纤维素的糖组成的降解和木结构内缩聚产物的形成。这些结果可以用真空的作用来解释,该作用允许除去挥发性降解产物,如有机酸,醛和呋喃,从而限制了多糖的酸性降解和挥发性副产物的再冷凝。针对不同的棕色和白色腐烂真菌进行的衰变耐久性测试表明,真空和氮气热处理的样品没有显着差异,所有样品均具有改进的耐腐性。根据这些结果,这篇短文的目的是报告真空对氮对热处理样品的机械性能的影响,并假设在真空下进行处理期间木材多糖的较低降解可减少机械性能的降低。为此,确定了弯曲时的断裂模量(MOR)和弹性模量(MOE)和布氏硬度(HB)。结果表明,在真空处理的木材样品中,机械性能的降解较低。

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  • 来源
    《Polymer Degradation and Stability》 |2013年第9期|1762-1765|共4页
  • 作者单位

    Laboratoire d'Etudes et de Recherche sur le Materiau Bois, EA 4370, Universite de Lorraine, Faculte des Sciences et Technologies, BP 70239, F-54506 Vandoeuvre-les-Nancy, France;

    Laboratoire d'Etudes et de Recherche sur le Materiau Bois, EA 4370, Universite de Lorraine, Faculte des Sciences et Technologies, BP 70239, F-54506 Vandoeuvre-les-Nancy, France;

    Laboratoire d'Etudes et de Recherche sur le Materiau Bois, EA 4370, Universite de Lorraine, Faculte des Sciences et Technologies, BP 70239, F-54506 Vandoeuvre-les-Nancy, France;

    Laboratoire d'Etudes et de Recherche sur le Materiau Bois, EA 4370, Universite de Lorraine, Faculte des Sciences et Technologies, BP 70239, F-54506 Vandoeuvre-les-Nancy, France;

    Laboratoire d'Etudes et de Recherche sur le Materiau Bois, EA 4370, Universite de Lorraine, Faculte des Sciences et Technologies, BP 70239, F-54506 Vandoeuvre-les-Nancy, France;

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  • 原文格式 PDF
  • 正文语种 eng
  • 中图分类
  • 关键词

    Beech; Degradation; Mechanical properties; Nitrogen; Thermal treatment; Vacuum;

    机译:山毛榉降解;机械性能氮;热处理;真空;

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