Structural evolution and degradation mechanism of Vectran~® fibers upon exposure to UV-radiation

摘要

Vectran~® fibers are widely used in military and aerospace industries as high performance fibers. However, they are susceptible to degradation and undergo structural changes when exposed to ultraviolet (UV) irradiation in service. The focus of this work is to investigate the photochemical aging behavior and mechanism of the Vectran~® fibers. The morphologies, mechanical properties, chemical structures and behaviors against UV irradiation have been studied. The tensile test results reveal that the tensile strength decreases quickly when the fibers are exposed to Xenon lamp irradiation. The morphology of the Vectran~® fiber surface is damaged after accelerated aging. Crystallinity content analysis illustrates that the degree of the fiber structural ordering is decreased due to irradiation. Fourier transformed infrared analyses (FT-IR) and X-ray photoelectron spectroscopy (XPS) analyses of the accelerated aged fibers prove the chemical structural changes of the Vectran~® fibers. For the first time, the possible photodegradation mechanism of Vectran~® fiber is proposed in both air and N_2 environments. The rate of degradation and number of chain scissions are greater in air than in N_2. The radicals generated by chain scissions can directly abstract a hydrogen atom or can react with O_2 creating hydroxyl OH/COOH end groups in air atmosphere. The diaryl ethers may be formed due to the replacement of the H atoms in aromatic rings for linking ud two aromatic rings.