Degradation under composting conditions of lysine-modified polyurethane based on PCL obtained by lipase biocatalysis

摘要

Enzymatic polymerization has a large potential as an environmentally friendly synthetic process. Lipase is a renewable catalyst with high catalytic activity from which it is possible to develop a versatile method for the production of sustainable polyurethanes. In this work oligomeric PCL-diol was synthesized using biocatalysis with immobilizedYarrowia lipolyticalipase (YLL) and diethyleneglycol as initiator. Then, two different linear polyurethanes were prepared. One was obtained directly from the previous synthesized PCL-diol and hexamethylene diisocyanate, named PU, and the other one has been obtained by incorporatingl-lysine amino acid as end group (lys-PU). PU and lys-PU disintegration under composting conditions was evaluated. The influence of the presence ofl-lysine on the disintegration performance of PU was studied by evaluating the disintegration degree, monitoring the weight loss. Structural and morphological changes were followed by Fourier transformed infrared spectroscopy (FTIR) and by scanning electron microscopy (SEM).